Evaluation of the Thermal Stabilization Effect of Maleic Anhydride Derivatives on Polyvinyl Chloride

Article Preview

Abstract:

Here, we synthesized a series of polymeric thermal stabilizers for polyvinyl chloride (PVC) based on maleic anhydride derivatives, including N-phenylmaleimide (NPMI), N-p-chlorophenyl maleimide (NCIPMI), N-p-nitrophenyl maleimide (NNOPMI), dibutyltin maleate (DBTM) and dioctyltin maleate (DOTM). Five specimens were prepared by mixing and rolling through a blending machine and a double-roller mixer, respectively. These samples were first subjected to thermal degradation in a 180°C hot oven, and fractions were collected every 10 min, followed by spotting on a slip of test paper. From the degree of color change in the test paper, the influences of these compounds on the thermal stability of PVC were estimated and such mechanisms were also discussed.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 535-537)

Pages:

1167-1170

Citation:

Online since:

June 2012

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] Radka Kalouskova, Miroslava Novotna, Zdenek Vymazal. Investigation of thermal stabilization of poly(vinyl chloride) by lead stearate and its ombination with synthetic hydrotalcite. Polymer Degradation and Stability, 85 (2004) 903-909.

DOI: 10.1016/j.polymdegradstab.2004.04.008

Google Scholar

[2] M.T. Benaniba, N. Belhaneche-Bensemra, G. Gelbard. Stabilizing effect of epoxidized sunflower oil on the thermal degradation of poly(vinyl chloride). Polymer Degradation and Stability, 74 (2001) 501–505.

DOI: 10.1016/s0141-3910(01)00170-7

Google Scholar

[3] Long Fang, Yihu Song, Xiaonan Zhu, Qiang Zheng. Influence of lanthanum stearate as a co-stabilizer on stabilization efficiency of calcium/zinc stabilizers to polyvinyl chloride. Polymer Degradation and Stability, 2009, 94(5), 845~850.

DOI: 10.1016/j.polymdegradstab.2009.01.024

Google Scholar

[4] Michael H. Fisch, Radu Bacaloglu, Keith Biesiada, Lawrence R. Brecker. Mechanism of organotin stabilization of poly(vinyl chloride). 1: The structure and equilibria of alkyltin thioqlycolates and their compatibility with PVC. Journal of Vinyl & Additive Technology, 5(1999) 40-44.

DOI: 10.1002/vnl.10305

Google Scholar