Solid-Solid Synthesis, Characterization and Thermal Decomposition of Thiourea Complex of Antimony Trichloride

Guo Qing Zhong; Mei Gu; Yu Qing Jia

doi:10.4028/www.scientific.net/AMR.549.126

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HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 549Solid-Solid Synthesis, Characterization and...

Solid-Solid Synthesis, Characterization and Thermal Decomposition of Thiourea Complex of Antimony Trichloride

Abstract:

The solid complex of antimony trichloride with thiourea was synthesized by solid-solid reaction or liquid state reaction of antimony trichloride and thiourea. The formula of solid complex is all SbCl₃[CS(NH₂)₂]₃. The crystal structure of the complex belongs to monoclinic system and the lattice parameters are: a = 1.2426 nm, b = 1.6396 nm, c = 1.9254 nm and β = 96.24° for solid-solid reaction, and a = 1.2343 nm, b = 1.6585 nm, c = 1.9252 nm and β = 96.46° for liquid state reaction, respectively. The infrared spectra reveal that antimony ion in the complex is coordinated only by the sulfur atom of CS(NH₂)₂. The possible pyrolysis reactions in the thermal decomposition process of the complex, the experimental and calculated percentage mass loss were also given.

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Periodical:

Advanced Materials Research (Volume 549)

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126-130

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.549.126

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Online since:

July 2012

Authors:

Guo Qing Zhong, Mei Gu, Yu Qing Jia

Keywords:

Complex of Antimony, Room Temperature Solid-Solid Synthesis, Thermal Decomposition, Thiourea, X-Ray Diffraction (XRD)

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