Synthesis of 5,10,15-Tris(4-nitrophenyl)-20-hydroxylphenylporphyrin and its Spectrum Study

Huan Bao Fa; Hui Qi; Wei Yin; Dan Qun Huo; Chang Jun Hou

doi:10.4028/www.scientific.net/AMR.549.269

Paper Titles

Influence of Polyols as a Co-Stabilizer on Stabilization Efficiency of Calcium/Zinc Stabilizers to PVC
p.251

Influence of Cellulase to Aggregation Structure of Bleached Softwood Pulp
p.255

Effect of Neutral Xylanase Pretreatment on ECF Bleaching of KP Bamboo Pulp with Low Kappa Number
p.260

Synthesis, Characterization of the Mn(II) Complex of Rutin and Interactions between the Complex and Serum Albumins
p.265

Synthesis of 5,10,15-Tris(4-nitrophenyl)-20-hydroxylphenylporphyrin and its Spectrum Study
p.269

Growth and Measurement of Mg Doped AlGaN/GaN Superlattice with Low Resistiviy
p.274

Adsorption Kinetics of Reactive Dyes on Silk with Octyl Butyl Dimethyl Ammonium Bromide as Accelerant
p.278

Structure, Acid Properties and Catalysis Performance of MCM-22 “Family” Zeolites on the Alkylation of Benzene with Propylene
p.283

Ionic Liquid-Catalyzed Synthesis of Diethylene Glycol
p.287

HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 549Synthesis of...

Synthesis of 5,10,15-Tris(4-nitrophenyl)-20-hydroxylphenylporphyrin and its Spectrum Study

Abstract:

5,10,15-Tris(4-nitrophenyl)-20-hydroxylphenylporph-yrin was synthesized by a novel method which was for the nitration of the phenyl groups of 5-(4-hydroxylphenyl)-10,15,20- triphenylporphyin(MHTPP) using NaNO2 and trifluoroacetic acid(TFA) and characterized using mass spectrometry, NMR spectroscopy, UV-visible, IR spectrometry. The mild reaction conditions produced higher yields and minimum macrocyclic degradation. Its fluorescence spectra was studied compared with MHTPP and tetraphenylporphyrin(TPP). The results showed that the absorption and emission bands of the product experienced red shifts and the fluorescence intensity weakened compared with MHTPP and TPP.

You might also be interested in these eBooks

Chemical Engineering and Material Properties II

View Preview

Info:

Periodical:

Advanced Materials Research (Volume 549)

Pages:

269-273

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.549.269

Citation:

Cite this paper

Online since:

July 2012

Authors:

Huan Bao Fa, Hui Qi, Wei Yin, Dan Qun Huo, Chang Jun Hou

Keywords:

Fluorescence, Nitration, Nitrophenylporphyrin, Synthesis

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

References

[1] R. Bonnett, A. Harriman and A.N. Kozyrev, Photophysics ofhalogenated porphyrins, J. Chem. Soc., Faraday Trans. 1, 88(1992) 763-769.

DOI: 10.1039/ft9928800763

Google Scholar

[2] Kessel, D. Luguya, R.; Vicente, M. G. H. Photochem. Photobiol. 2003, 78, 431–435.

Google Scholar

[3] Jaquinod, L. The porphyrin handbook; Kadish, K. M., Smith K.M., Guilard, R., Eds. Academic: Boston, 2000; Vol. 1, p.201–237.

Google Scholar

[4] Robert G. Little.J. Heterocyclic Chem. [J], 1981, (18) : 129—133.

Google Scholar

[5] Raymond Luguya, Laurent Jaquinod, Frank R. Fronczek, M. Tetrahedron 60 (2004) 2757–2763.

Google Scholar

[6] Meng, G. G.; James, B. R.; Skov, K. A. J. Can. J. Chem. 1994, 72, 1894–(1909).

Google Scholar

[7] M. Gouterman, in: The porphyrins, Vol. 3, ed. D. Dolphin Academic Press, New York, 1978) ch. 1.

Google Scholar

[8] H. Imahori, K. Tamaki, Y. Araki, Y. Sekiguchi, O. Ito, Y. Sakata, S. Fukuzumi, J. Am. Chem. Soc. 124 (2002) 5165–5174.

DOI: 10.1021/ja016655x

Google Scholar

[9] K. Kano, T. Miyake, K. Uomoto, T. Sato, T. Ogawa, S. Hashimoto, Chem. Lett. (1983) 1867.

Google Scholar

[10] K. Kano, T. Nakajima,M. Takei, S. Hashimoto, Bull. Chem. Soc. Jpn. 60 (1987) 1281.

Google Scholar

[11] A. Henriksson, B. Roos and M. Sundbom, Theoret. Chim. Acta . 27 (1972) 303.

Google Scholar