For Libraries For Publication Open Access Downloads About Us Contact Us
Paper Titles
Synthesis, Characterization of the Mn(II) Complex of Rutin and Interactions between the Complex and Serum Albumins
p.265
Synthesis of 5,10,15-Tris(4-nitrophenyl)-20-hydroxylphenylporphyrin and its Spectrum Study
p.269
Growth and Measurement of Mg Doped AlGaN/GaN Superlattice with Low Resistiviy
p.274
Adsorption Kinetics of Reactive Dyes on Silk with Octyl Butyl Dimethyl Ammonium Bromide as Accelerant
p.278
Structure, Acid Properties and Catalysis Performance of MCM-22 “Family” Zeolites on the Alkylation of Benzene with Propylene
p.283
Ionic Liquid-Catalyzed Synthesis of Diethylene Glycol
p.287
Solid-Solid Reaction Preparation for Nanoparticles of Bioinorganic Complex of Bismuth and Serine at Room Temperature
p.292
Hydrogenolysis of Glycerol on Supported Ru-Co Bimetallic Catalysts
p.297
Theoretical Study on the Reaction of Et3GeCH=CH2 with Et3SiOH
p.301

Structure, Acid Properties and Catalysis Performance of MCM-22 “Family” Zeolites on the Alkylation of Benzene with Propylene

Article Preview

Abstract:

MCM-22 “family” zeolites (MCM-22, MCM-49 and MCM-56) have been synthesized hydrothermally by dynamic method. All materials were characterized by different techniques, such as XRD, N2 adsorption-desorption and NH3-TPD. The catalyst performance of MCM-22 “family” zeolites have been studied on the alkylation of benzene with propylene in liquid phase. Result shows that MCM-22 “family” zeolites are excellent alkylation catalysts for the produce of cumene. Compared to MCM-22 and MCM-49, MCM-56 shows higher catalytic activity in a relatively low reaction temperature and higher monoalkylation selectivity in a relatively low benzene-to-propylene ratio.

You might also be interested in these eBooks
Chemical Engineering and Material Properties II View Preview

Info:

Periodical:

Advanced Materials Research (Volume 549)

Pages:

283-286

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.549.283

Citation:

Cite this paper

Online since:

July 2012

Authors:

Fei Zhao, Yu Zhang, Shu Dong Geng, Lian Fa Chen, Wei Wang

Keywords:

Alkylation, Cumene, MCM-22 Family Zeolite

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

References

[1] Perego Carlo, Ingallina Patrizia: Catalysis Today, Vol. 73 (2002), p.3.

Google Scholar

[2] Thomas F. Degan Jr., C. Morris Smith, Chaya R. Venkat: Applied Catalysis A: General, Vol. 221 (2001), p.283.

Google Scholar

[3] A. Corma, V. Martnez-Soria, E. Schnoeveld: Journal of Catalysis, Vol. 192 (2000), p.163.

Google Scholar

[4] Jiquan Fu, Chuenhua Ding: Catalysis Communication, Vol. 6 (2005), p.770.

Google Scholar

[5] M.E. Leonowicz, J.A. Lawton, S.L. Lawton, M.K. Rubin: Science, Vol. 264 (1994), p. (1910).

Google Scholar

[6] A. Corma, Moliner Manuel: J. Catal., Vol. 241(2006), p.312.

Google Scholar

[7] A. Corma, U. Diaz, V. Fornes: J. Catal., Vol. 191 (2000), p.218.

Google Scholar

[8] Ning Xu, Tonghao Wu, DongYang Wang et al.: Chem. J. Chinese University, Vol. 11 (2001), p.1898.

Google Scholar

[9] Yu Zhang, Haijun Xing, Peng Wu: Reaction Kinetics and Catalysis Letters, Vol. 90 (2007), p.45.

Google Scholar

[10] Yu Zhang, Haijun Xing, Tonghao Wu: Chem. J. Chinese University, Vol. 30(2009), p.1380.

Google Scholar

[11] Piaoping Yang, Jianfeng Yu, Zhenlv Wang: Catalysis Communications, Vol. 6(2005), p.107.

Google Scholar

[12] A.S. Fung, S.L. Lawton, J. Roth: US 5, 362, 697. (1994).

Google Scholar

[13] G. G. Juttu, R.F. Lobo: Micropor. Mesopor. Mater., Vol. 40(2000), p.9.

Google Scholar

© 2025 Trans Tech Publications Ltd. All rights are reserved, including those for text and data mining, AI training, and similar technologies. For open access content, terms of the Creative Commons licensing CC-BY are applied.
Scientific.Net is a registered trademark of Trans Tech Publications Ltd.