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HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 549Hydrogenolysis of Glycerol on Supported Ru-Co...

Hydrogenolysis of Glycerol on Supported Ru-Co Bimetallic Catalysts

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Abstract:

The hydrogenolysis of biomass-derived glycerol was studied on Ru-Co bimetallic catalysts, including Ru-Co/TiO₂, Ru-Co/ZrO₂, Ru-Co/SiO₂ and Ru-Co/γ-Al₂O₃. The addition of Co to the Ru-based catalysts can promote the selectivity to 1,2-propanediol (1,2-PDO). The support material and Ru/Co atomic ratio has a significant effect on the catalytic performance. Ru-Co/ZrO₂ exhibited the best performance as regard to both the activity and the selectivity to 1,2-PDO. Co is a promising second metal component to adjust the catalytic properties of Ru-based catalysts for the selective hydrogenolysis of glycerol.

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Chemical Engineering and Material Properties II

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Periodical:

Advanced Materials Research (Volume 549)

Pages:

297-300

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.549.297

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Online since:

July 2012

Authors:

Jian Feng, Bin Xu, Wei Dong Jiang, Wei Xiong, Jin Bo Wang

Keywords:

1,2-Propanediol, Glycerol, Hydrogenolysis, Ru-Co Bimetallic Catalyst

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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[1] J. Feng, M.L. Yuan, H. Chen and X.J. Li: Prog. Chem. Vol. 19 (2007), p.651.

[2] Y. Nakagawa and K. Tomishige: Catal. Sci. Technol. Vol. 1 (2011), p.179.

[3] T. Miyazawa, Y. Kusunoki, K. Kunimori and K. Tomishige: J. Catal. Vol. 240 (2006), p.213.

[4] T. Miyazawa, S. Koso, K. Kunimori and K. Tomishige, Appl. Catal. A Vol. 318 (2007), p.244.

[5] T. Miyazawa, S. Koso, K. Kunimori and K. Tomishige: Appl. Catal. A Vol. 329 (2007), p.30.

[6] M. Balaraju, V. Rekha, P.S. Sai-Prasad, B.L.A. Prabhavathi-Devi, R.B.N. Prasad and N. Lingaiah: Appl. Catal. A Vol. 354 (2009), p.82.

[7] S. Bolado, R.E. Treviño, M.T. García-Cubero, G. González-Benito: Catal. Commun. Vol. 6 (2010), p.122.

[8] J. Feng, J.B. Wang, Y.F. Zhou, H.Y. Fu, H. Chen and X.J. Li: Chem. Lett. Vol. 36 (2007), p.1274.

[9] J. Feng, H.Y. Fu, J.B. Wang, R.X. Li, H. Chen and X.J. Li: Catal. Commun. Vol. 9 (2008), p.1458.

[10] J. Feng, W. Xiong, Y. Jia, J.B. Wang, D.R. Liu, H. Chen and X.J. Li: Chin. J. Catal. Vol. 32 (2011), p.1545.

[11] M. Balaraju, V. Rekha, B.L.A. Prabhavathi-Devi, R.B.N. Prasad, P.S. Sai-Prasad and N. Lingaiah: Appl. Catal. A Vol. 384 (2010), p.107.

[12] E.S. Vasiliadou, E. Heracleous, I.A. Vasalos, A.A. Lemonidou: Appl. Catal. B Vol. 92 (2009), p.90.

[13] D. Roy, B. Subramaniam, R.V. Chaudhari: Catal. Today Vol. 156 (2010), p.31.

[14] L. Ma, D.H. He and Z.P. Li: Catal. Commun. Vol. 9 (2008), p.2489.

[15] T. Jiang, Y.X. Zhou, S.G. Liang, H.Z. Liu and B. X Han: Green chem. Vol. 11 (2009), p.1000.

[16] Z.J. Wu, Y.Z. Mao, X.X. Wang and M.H. Zhang: Green chem. Vol. 13 (2011), p.1311.

[17] L. Ma and D.H. He: Catal. Today Vol. 149 (2010), p.148.

[18] X. H Guo, Y. Li and W. Song: Catal. Lett. Vol. 141 (2011), p.1458.