Growth Conditions for Carbon Nanotubes and Helical Nanofibers on Copper Substrates Using Sparked Catalysts

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Carbon nanotubes (CNTs) and helical nanofibers (HNFs) were selectively grown on copper substrates by chemical vapor deposition using acetylene as a carbon source. The experiments were carried out by using Ni, Fe and Co as single and co-catalysts which were deposited onto the substrates by a sparking method. The catalyst-coated copper substrates were heated at 750°C in a mixed-gas-flowing tube furnace, at an argon flow rate of 100 ml/min and various acetylene flow rates of 3, 5 and 10 ml/min. The larger diameter of HNFs was grown only on Ni and Ni-Fe catalysts at the acetylene flow rates of 5 and 10 ml/min whereas the uniform smaller diameter of CNTs was preferentially grown on Fe-Co and Ni-Fe catalysts at the flow rate of 3 ml/min. We suggest that Co likely prevents the formation of HNFs whereas Ni promotes.

Info:

Periodical:

Advanced Materials Research (Volumes 55-57)

Main Theme:

Edited by:

Tawee Tunkasiri

Pages:

561-564

DOI:

10.4028/www.scientific.net/AMR.55-57.561

Citation:

B. Toboonsung and P. Singjai, "Growth Conditions for Carbon Nanotubes and Helical Nanofibers on Copper Substrates Using Sparked Catalysts", Advanced Materials Research, Vols. 55-57, pp. 561-564, 2008

Online since:

August 2008

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$35.00

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