Effects of Supports and Reduction Temperature on Pt Dispersion of HI Decomposition Catalyst

Article Preview

Abstract:

Pt catalysts have been researched and used for HI decomposition. Specifically, the effects of supports and reduction temperature on metal dispersion were investigated in this paper. Metal dispersion was high measured, in the order of Pt/Al2O3, Pt/ZrO2, and Pt/SiO2. HI conversion results coincided with the metal dispersion. With effect on reduction temperature, Pt dispersion was measured as 2.9 %, 26 %, and 60 % each 1173K, 973K, and 773 K. In addition, HI conversion presented 7.8%, 16.3%, and, 19.4% respectively. Consequently, Pt dispersion, influenced by supports and reduction temperature was considered to be crucial role in HI conversion.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 550-553)

Pages:

392-395

Citation:

Online since:

July 2012

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] J. E. Funk, "Thermochemical production of hydrogen via multistage water splitting process", International Journal of Hydrogen Energy, Vol. 1, 1976. pp.33-43.

DOI: 10.1016/0360-3199(76)90007-0

Google Scholar

[2] M. Nomura, S. Kasahara, H. Okuda, S. Nakao, "Evalution of the IS process featuring membrane techniques by total thermal efficiency", International Journal of hydrogen Energy, Vol/ 30, 2005, pp.1465-1473.

DOI: 10.1016/j.ijhydene.2004.10.022

Google Scholar

[3] M. Dokiya, T. Kemetama, K. Fukuda, "Thermochemical Hyrogen preperation -part V. A Feasibility studt of the sulfur iodine Cycle", Hydrogen Energy, Vol. 4, pp.267-277.

DOI: 10.1016/0360-3199(79)90002-8

Google Scholar

[4] D. O'keefe, C. Allen, G, Besenbruch, L. Browon, J. Norman, and R. Sharp, "Preliminary results from bench-scale testing of a sulfur-iodine thermochemical water-splitting cycle", Int hydrogen Energy, 7, 1982, p.381

DOI: 10.1016/0360-3199(82)90048-9

Google Scholar

[5] K. Onuki, Y. Inagaki, R. Hido, and Y. Tachibana, "Research and development on nuclear hydrogen production using HTGR at JAERI", Progress in Nuclear Energy, 47, 2005, p.496.

DOI: 10.1016/j.pnucene.2005.05.050

Google Scholar

[6] Marius Vaarkamp, Jeffrey T. Millerb, Frank S. Modica, Diek C. Koningsberger, Journal of Catalysis, 163(2), 294 (1996).

Google Scholar

[7] Ja Hun Kwak, Jianzhi Hu1, Donghai Mei, Cheol Woo Yi, Do Heui Kim, Charles H. F. Peden1, Lawrence F. Allard, Janos Szanyi, Science, 325, 1670 (2009).

Google Scholar

[8] G.-M. Schwab. Adv. Catal., 27, 1 (1978) .

Google Scholar

[9] D.J. Smith, D. White, T. Baird, J.R. Fryer, The characterization of a model platinum/alumina catalyst by high-resolution electron microscopy, J.Catal. 81 (1983) 107–-118.

Google Scholar

[10] Abhaya K. Datye, Qing Xu, Karl C. Khara, Jon M. McCary, Particle size distribytion in heterogeneous catalyst : What do they tell us about the sintering mechanism?, Catalysis today, 111 (2006) 59-67.

DOI: 10.1016/j.cattod.2005.10.013

Google Scholar