Supported CuO and ZnO Catalyst for Hydrogenation of Carbon Dioxide to Methyl Alcohol

Chul Min Park; Won Ju Ahn; Woong Kyu Jo; Jin Hun Song; Chang Yeop Oh; Young Shin Jeong; Ki Joong Kim; Min Chul Chung; Woon Jo Jeong; Kwon Pil Park; Ho Geun Ahn

doi:10.4028/www.scientific.net/AMR.550-553.396

Paper Titles

Kinetic Study of the Oxidative Dehydrogenation of Cyclohexane over Mg₃(VO₄)₂ Catalyst
p.379

Deactivation Behavior of Cu_XCe_1-XO_2-X/SBA-15/Cordierite Monolithic Catalysts for Catalytic Combustion of CO
p.383

REE Lanthanum Doping Influence on the Photocatalysis Properties of Titanium Dioxide
p.388

Effects of Supports and Reduction Temperature on Pt Dispersion of HI Decomposition Catalyst
p.392

Supported CuO and ZnO Catalyst for Hydrogenation of Carbon Dioxide to Methyl Alcohol
p.396

Synthesis of Benzaldehyde 1, 2-Propanediol Acetal by Using Ionic Liquid [Hmim]HSO₄ as Catalyst
p.400

Preparation and Photocatalytic Activity of Bi Doped TiO₂ with Visible-Light Response
p.404

Research on Catalytic Combustion of Low Concentration Methane in Combustion Channel of Compact Reformer
p.411

Reaction Characteristic of MeAPSO-34 (Me=Mn, Co) Catalysts for Olefins Production from Dimethyl Ether
p.416

HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 550-553Supported CuO and ZnO Catalyst for Hydrogenation...

Supported CuO and ZnO Catalyst for Hydrogenation of Carbon Dioxide to Methyl Alcohol

Abstract:

If the surface of the titanium chips (TC) was modified by thermal treatment under air atmosphere, it could be reused as catalyst support or photocatalytic materials. TC-supported CuO and ZnO catalysts were prepared by impregnation (IMP) method and co-precipitation (CP) method using cupric nitrate and zinc nitrate solution as precursors. Loading of CuO and ZnO on TC was 40.6wt% and 50.3wt%, respectively. The catalytic activity for CO₂ hydrogenation was investigated using a flow-typed reactor under various pressures. Conversion of carbon dioxide to methyl alcohol over the CuO-ZnO/TC catalyst by CP and IMP methods were ca. 22% and ca. 10%, respectively. Conversion of carbon dioxide over CuO-ZnO/TC catalyst by CP method was increased with increasing reaction temperature in ranging of 15atm to 30 atm. Maximum selectivity and yield to methyl alcohol over CuO-ZnO/TC catalyst at 250°C were ca. 90% at 20 atm and ca. 18.2% at 30 atm, respectively.