Optimization of Base-Catalyzed Biodiesel Production from Waste Frying Oil

Article Preview

Abstract:

Keywords: Biodiesel, Base catalyst, Waste Fried Oil, Orthogonal design Abstract: In this article the biodiesel production procedure of base-catalyzed esterification was studied, and the optimal conditions of preparation were brought up. By applying orthogonal design, the optimal conditions of base-catalyzed esterification from waste frying oil with acid value of 4 mg/l KOH were: methanol/oil ratio, 8:1; catalyst dose, 1% oil weight; temperature, 85°C; reaction time, 1.5 h. The maximum oil conversion rate of 90% was achieved. The influence of each factor on the oil production in descending order was: methanol/oil ratio > catalyst dose > temperature > reaction time. The biodiesel refinement was carried out with three types of rinsing solutions: distilled water, satirized NaCl solvent and glacial acetic acid. Rinsing times, soap removing rate and final acid value of the biodiesel were considered as the critical factors in evaluating the effectiveness of the rinsing solution on the biodiesel refinement. The results turned out that the most suitable rinsing method for industrial application was rinsing with saturated NaCl solvent.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 550-553)

Pages:

540-543

Citation:

Online since:

July 2012

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] Li.X, and Wang.J. (2008).Feasibility analysis of the development of biodiesel and industrial proposal.Hubei Agricultural Sciences, 11, 1364-1368.

Google Scholar

[2] Li.W, Yang. R, Zhang.X, and Gao.W.(2008). Research on the Optimal Reaction Condition for the Biodieselfrom Waste Oil of Restaurant. Journal Of Liaoning University, 2, 148-150.

Google Scholar

[3] Tan.L. (2007).Current situation and development: Trend of the research and application of preparing biodiesel by WOF. Chamical Prodiction And Technology, 1, 29-34.

Google Scholar

[4] Huang.Y, Tang.H and Chen.W. (2009). Acid-base catalyst in the biodiesel produce. Cereals and Oils Processing, 11, 66-69.

Google Scholar

[5] Fu.H. Study of turpentine garbagefat transesterification preparartion of biodiesel (2007) Nanchang University.

Google Scholar

[6] Jiang.X. (2007).Improve the accuracy of determination of acid value of oil. Meat Industry, 9, 43-44.

Google Scholar

[7] Wang.P, and Wang.X. (2011). Preparation of Biodiesel from Waste Cooking Oil and Ethanol. Anhui Chemical Industry, 2, 39-43.

Google Scholar

[8] Guo.Y, and Chen.F. (2011). Refinery operation optimization for purification of biodiesel product by alkaline-catalized process.Biomass Chemical Engineering, 4, 11-16.

Google Scholar