Electrochemically Deposited Thermoelectric Bismuth-Telluride Films

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Abstract:

Thermoelectric bismuth-telluride films were successfully prepared from nitric acid aqueous solution with ethylene glycol on Ti-sputtered silicon substrates by electrochemical deposition techniques. Cyclic voltammograms (CV), X-ray diffraction (XRD), scanning electron microscope (SEM) and energy dispersive spectroscopy (EDS) were used to investigate nucleation process, the crystal structures, morphologies and compositions of the bismuth-telluride films. The results show that the materials are Bi-rich, exhibiting preferred (110) orientation with rhombohedral structure. The crystallite size of films was calculated based on Scherrer’s equation and found to be 18-20 nm.

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Advanced Materials Research (Volumes 557-559)

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1811-1814

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July 2012

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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[1] G.J. Snyder and E.S. Toberer: Nature Materials vol. 7 (2008), pp.105-114.

Google Scholar

[2] S.K. Mishra, S. Satpathy, and O. Jepsen: Journal of Physics-Condensed Matter vol. 9 (1997), pp.461-470.

Google Scholar

[3] D.H. Kim, E. Byon, G.H. Lee, and S. Cho: Thin Solid Films vol. 510 (2006), pp.148-153.

Google Scholar

[4] Y.-Y. Li, G. Wang, X.-G. Zhu, M.-H. Liu, C. Ye, X. Chen, Y.-Y. Wang, K. He, L.-L. Wang, X.-C. Ma, H.-J. Zhang, X. Dai, Z. Fang, X.-C. Xie, Y. Liu, X.-L. Qi, J.-F. Jia, S.-C. Zhang, and Q.-K. Xue: Advanced Materials vol. 22 (2010), pp.4002-4007.

DOI: 10.1002/adma.201000368

Google Scholar

[5] A. Giani, F. PascalDelannoy, A. Boyer, A. Foucaran, M. Gschwind, and P. Ancey: Thin Solid Films vol. 303 (1997), pp.1-3.

DOI: 10.1016/s0040-6090(97)00089-8

Google Scholar

[6] A. Dauscher, A. Thomy, and H. Scherrer: Thin Solid Films vol. 280 (1996), pp.61-66.

DOI: 10.1016/0040-6090(95)08221-2

Google Scholar

[7] A.L. Prieto, M.S. Sander, M. Martin-Gonzalez, R. Gronsky, T. Sands, and A.M. Stacy: Journal of the American Chemical Society vol. 123 (2001), pp.7160-7161.

Google Scholar

[8] B.Y. Yoo, C.K. Huang, J.R. Lim, J. Herman, M.A. Ryan, J.P. Fleurial, and N.V. Myung: Electrochimica Acta vol. 50 (2005), p.4371.

DOI: 10.1016/j.electacta.2005.02.016

Google Scholar

[9] M.S. Martin-Gonzalez, A.L. Prieto, R. Gronsky, T. Sands, and A.M. Stacy: Journal of the Electrochemical Society vol. 149 (2002), p. C546-C554.

Google Scholar

[10] S. Michel, S. Diliberto, C. Boulanger, N. Stein, and J.M. Lecuire: Journal of Crystal Growth vol. 277 (2005), pp.274-283.

Google Scholar

[11] D. Pinisetty, D. Davis, E.J. Podlaha-Murphy, M.C. Murphy, A.B. Karki, D.P. Young, and R.V. Devireddy: Acta Materialia vol. 59 (2011), pp.2455-2461.

DOI: 10.1016/j.actamat.2010.12.047

Google Scholar