Preparation, Characterization and their Performance of the Supported Nanoscale Zero-Valent Iron Materials with Different Iron Contents

Article Preview

Abstract:

Taking the organic modified montmorillonite as a carrier and dispersant, the supported nanoscale zero-valent iron materials with different iron contents were synthesized through the ferrous sulfate (FeSO4) and the sodium borohydride (NaBH4) in it. The structure and morphology of the materials were characterized by X-ray diffraction(XRD) and scanning electron microscopy(SEM). Finally, the performances of the supported nanoscale zero-valent iron were studied by high-performance liquid chromatography to determine the adsorption and degradation of 4-chlorophenol. The results indicate that the supported nanoscale zero-valent iron was well dispersed,different iron dosages imposed a visible effect on the morphology and particle diameter of iron;the degradation of 4-chlorophenol resulted from adsorption and degradation processes. Materials with different iron contents exhibited significantly different performance levels in terms of 4-chlorophenol adsorption and degradation.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 573-574)

Pages:

155-162

Citation:

Online since:

October 2012

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] Doong R, Chen K, Tsai H. Reductive dechlorination of carbon tetrachloride and tetrachloroethylene by zero valent silicon–iron reductants. Environmental Science & Technology, Vol. 37(2003), pp.2575-2581.

DOI: 10.1021/es020978r

Google Scholar

[2] James T. Nurmi, Paul G. Tratnyek, Vaishnavi Sarathy, et al. Characterization and properties of metallic iron nanoparticles: spectroscopy, electrochemistry, and kinetics. Environmental Science & Technology , Vol. 39(2005), pp.1221-1230.

DOI: 10.1021/es049190u

Google Scholar

[3] Hocheol S, Carraway ER. Reduction of chlorinated ethanes by nanosized zero-valent iron: kinetics, pathways, and effects of reaction conditions. Environ Sci Technol, Vol. 39(2005), pp.6237-6245.

DOI: 10.1021/es048262e

Google Scholar

[4] Kim G, Jeong W, Choe S. Dechlorination of atrazine using zero-valent iron (Fe0) underneutral pH conditions. J Hazard Mater, Vol. 155(2008), pp.502-506.

DOI: 10.1016/j.jhazmat.2007.11.092

Google Scholar

[5] Varanasi P, Fullana A, Sidhu S. Remediation of PCB contaminated soils using iron nano-particles. Chemosphere, Vol. 66, No6(2007), pp.1031-1038.

DOI: 10.1016/j.chemosphere.2006.07.036

Google Scholar

[6] C.B. Wang, W.X. Zhang, Synthesizing nanosca le iron particles for rapid and complete dechlorination of TCE and PCBs, Environ. Sci. Technol. Vol. 31(1997), pp.2154-2156.

DOI: 10.1021/es970039c

Google Scholar

[7] Phenrat T, Saleh N, Sirk K, Tilton RD, et al. Aggregation and sedimentation of aqueous nanoscale zerovalent iron dispersions. Environmental Science & Technology , Vol. 41(2007), pp.284-290.

DOI: 10.1021/es061349a

Google Scholar

[8] Üzüm Ç, Shahwan T, Eroğlu A E. et al. Synthesis and characterization of kaolinite-supported zero-valent iron nanoparticles and their application for the removal of aqueous Cu2+ and Co2+ ions. Applied Clay Science, Vol. 43, No2(2009), pp.172-181.

DOI: 10.1016/j.clay.2008.07.030

Google Scholar

[9] Li Z H, Willm C, Alley J, et al. A shift in pathway of iron-mediated perchloroethylene reduction in the presence of sorbed surfactant-a column study. Water Research, Vol. 40, No20(2006), pp.3811-3819.

DOI: 10.1016/j.watres.2006.08.025

Google Scholar

[10] Churchman GJ, Gates WP, Theng BKG, et al. Clays and clay minerals for pollution control. In: Bergaya F, Theng BKG, Lagaly G, editors. Handbook of clay science, developments in clay science[M]. Amsterdam: Elsevier; 2006. 625–75.

DOI: 10.1016/s1572-4352(05)01020-2

Google Scholar

[11] Li J, Li Y, Dong H. Controlled release of herbicide acetochlor from clay/carboxylmethyl-cellulose gel formulations. Journal of Agricultural and Food Chemistry , Vol. 56(2008), pp.1336-1342.

DOI: 10.1021/jf072530l

Google Scholar

[12] Li J, Li Y, Lu J. Adsorption of herbicides 2, 4-D and acetochlor on inorganic–organic bentonites. Applied Clay Science , Vol. 46(2009), pp.314-318.

DOI: 10.1016/j.clay.2009.08.032

Google Scholar

[13] Belkhadem F, Maldonado A, Siebenhaar B, et al. Microcalorimetric measurement of the acid properties of pillared clays prepared by competitive cation exchange. Applied Clay Science , Vol. 39(2008), pp.28-37.

DOI: 10.1016/j.clay.2007.04.005

Google Scholar

[14] Wang J L,Horan N,Stentiford E,et al. Bioadsorption of pentachlorophenol(PCP) from aqueous solution by activated sludge biomass. Bioresouce Technology, 2000, 75: 157-161. Vol. 75(2000), pp.157-161.

DOI: 10.1016/s0960-8524(00)00041-9

Google Scholar

[15] G.V. Lowry, K.M. Johnson. Congener-specific dechlorination of dissolved PCBs by microscale and nanoscale zerovalent iron in a water/methanol solution, Environmental Science & Technology, Vol. 38(2004), pp.5208-5216.

DOI: 10.1021/es049835q

Google Scholar

[16] Zhu L Z, LI Y M, ZHANG J Y, et al. Sorption of organobentonites to some organic pollutants in water . Environmental Science & Technology, 1997, 31(5): 1407–1410. Vol. 31, No. 5(1997), pp.1407-1410.

DOI: 10.1021/es960641n

Google Scholar

[17] HU L J, Li Y M. Removal of nitrobenzene from synthetic wastewater by nanoscale zero-valent iron supported on organobentonite . Acta Scientiae circumstantite, Vol. 28, No6(2008), pp.1107-1112.

Google Scholar

[18] Shahwan T, Üzüm Ç, Eroğlu A E. et al. Synthesis and characterization of bentonite/iron nanoparticles and their application as adsorbent of cobalt ions. Applied Clay Science, Vol. 47(2010), pp.257-262.

DOI: 10.1016/j.clay.2009.10.019

Google Scholar

[19] Fan M D, Yuan P, Chen T H, et al. Synthesis characterazation and size control of zerovalent iron nanoparticles anchored on montmorillonite[J]. Chinese Science Bulletin, Vol. 55, No. 11(2010), pp.1092-1099.

DOI: 10.1007/s11434-010-0062-1

Google Scholar

[20] XU Xin-hua, WEI Jian-jun, WANG Da-hui. Studies on dechlorination of chlorophenols with Pd/Fe and nanoscale Pd/Fe [J]. China Environmental Science, 2004, 24(1): 76-80. Vol. 24, No, 1(2004), pp.76-80.

Google Scholar