Preparation and Photocatalytic Performance of Nanostructural WO3 Induced by Ion in Hydrothermal Synthesis

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WO3 nanocrystals have been successfully synthesized via an ion induced auxiliary hydrothermal method. The experiment products were characterized by powder X-ray diffraction (XRD) and the Photocatalytic oxidation performance of products were characterized by using the photocatalytic oxidation of methyl orange under the condition of hydrogen peroxide. The optimal amount of catalyst required for catalytic oxidation experiments and the concentration of methyl orange (MO) were determined. The experimental results indicated that with he enhancement of metallicity in alkali main group, the photocatalytic activity of the WO3 induced by alkali metal cation increased; The SO42- has higher induce catalytic activity than Cl- when the type and quantity of cation are the same; however, the ion induction on the impact of surface area is quite different, and it founded that they comply with this regular pattern, that is Na+> K+> Li+ and SO42-> Cl-.

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535-538

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October 2012

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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[1] Jae Ok Lee, Young-Hoon Song, Min Suk Cha and Seock Joon Kim. Effects of Hydrocarbons and Water Vapor on NOx Using V2O5−WO3/TiO2 Catalyst Reduction in Combination with Nonthermal Plasma. Ind. Eng. Chem. Res., Vol. 46 (2007), p.5570.

DOI: 10.1109/plasma.2003.1229015

Google Scholar

[2] Liang Chen, Junhua Li and Maofa Ge. Promotional Effect of Ce-doped V2O5-WO3/TiO2 with Low Vanadium Loadings for Selective Catalytic Reduction of NOx by NH3. J. Phys. Chem. C, Vol. 113 (2009), p.21177.

DOI: 10.1021/jp907109e

Google Scholar

[3] Oliver Kröcher and Martin Elsener. Combination of V2O5/WO3−TiO2, Fe−ZSM5 and Cu−ZSM5 Catalysts for the Selective Catalytic Reduction of Nitric Oxide with Ammonia. Ind. Eng. Chem. Res., Vol. 47 (2008), p.8588.

DOI: 10.1021/ie800951a

Google Scholar

[4] Jinzhan Su, Liejin Guo, Ningzhong Bao and Craig A. Grimes. Nanostructured WO3/BiVO4 Heterojunction Films for Efficient Photoelectrochemical Water Splitting. Nano Lett., Vol. 11 (2011), p. (1928).

DOI: 10.1021/nl2000743

Google Scholar

[5] Hyoung-il Kim, Jungwon Kim, Wooyul Kim and Wonyong Choi. Enhanced Photocatalytic and Photoelectrochemical Activity in the Ternary Hybrid of CdS/TiO2/WO3 through the Cascadal Electron Transfer. J. Phys. Chem. C, Vol. 115 (2011), p.9797.

DOI: 10.1021/jp1122823

Google Scholar

[6] Yuping He, Zhenyu Wu, Limin Fu, Chaorong Li, Yanming Miao, Li Cao, Haiming Fan and Bingsuo Zou. Photochromism and Size Effect of WO3 and WO3−TiO2 Aqueous Sol. Chem. Mater., Vol. 15 (2003), p.4039.

DOI: 10.1021/cm034116g

Google Scholar

[7] Q. Xiang, G. F. Meng, H. B. Zhao, Y. Zhang, H. Li, W. J. Ma and J. Q. Xu. Au Nanoparticle Modified WO3 Nanorods with Their Enhanced Properties for Photocatalysis and Gas Sensing. J. Phys. Chem. C, Vol. 114 (2010), p. (2049).

DOI: 10.1021/jp909742d

Google Scholar

[8] Dezeng Li, Guangming Wu, Guohua Gao, Jun Shen and Fuqiang Huang. Ultrafast Coloring-Bleaching Performance of Nanoporous WO3–SiO2 Gasochromic Films Doped with Pd Catalyst. ACS Appl. Mater. Interfaces, Vol. 3 (2011), p.4573.

DOI: 10.1021/am200781e

Google Scholar

[9] Kang Yong Song, Myun Kyu Park, Young Tae Kwon, Hyun Woo Lee, Won Jo Chung and Wan In Lee. Preparation of Transparent Particulate MoO3/TiO2 and WO3/TiO2 Films and Their Photocatalytic Properties. Chem. Mater., Vol. 13 (2001), p.2349.

Google Scholar

[10] Kevin Sivula, Florian Le Formal and Michael Grätzel. WO3−Fe2O3 Photoanodes for Water Splitting: A Host Scaffold, Guest Absorber Approach. Chem. Mater., Vol. 21 (2009), p.2862.

DOI: 10.1021/cm900565a

Google Scholar

[11] Adam Lewera, Laure Timperman, Agata Roguska and Nicolas Alonso-Vante. Metal–Support Interactions between Nanosized Pt and Metal Oxides (WO3 and TiO2) Studied Using X-ray Photoelectron Spectroscopy. J. Phys. Chem. C, Vol. 115 (2011), p.20153.

DOI: 10.1021/jp2068446

Google Scholar

[12] Gratian R Bamwenda, Hironori Arakawa. The visible light induced photocatalytic activity of tungsten trioxide powders. Applied Catalysis A-general, Vol. 210(2001), p.181.

DOI: 10.1016/s0926-860x(00)00796-1

Google Scholar