Synthesis of Starch Graft Copolymer Dispersant and its Application Performance in Coal-Water Slurry

Article Preview

Abstract:

In this study, a new starch graft copolymer dispersant for Chinese Shenhua coal-water slurry (CWS) was prepared by radical polymerization using styrene sulfonate (SSS), hydroxyethyl acrylate (HEA) and methyl acrylic acid (MAA) as graft monomers in oxidation-reduction initiator system. The apparent viscosity, static stabilization and rheology of Shenhua coal-water slurry prepared with the dispersant have been were investigated. The experimental results demonstrate that the CWS gives the minimal viscosity of 826 mPas at coal concentration of 66 wt%, dispersant dosage of 0.5 wt% and shear rate of 100 s-1. Bleeding ratio tests indicate the starch graft copolymer can stabilize the slurry. The rheological behavior of the prepared CWS can be described by the pseudo-plastic fluid model. On the basis of the above, the starch graft copolymer dispersant has broad prospect for the application for CWS.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 581-582)

Pages:

330-333

Citation:

Online since:

October 2012

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] F. Boylu, H. Dincer, G. Atesok, Effect of coal particle size distribution, volume fraction and rank on the rheology of coal-water slurries, Fuel Proces. Technol. 85 (2004) 241-250.

DOI: 10.1016/s0378-3820(03)00198-x

Google Scholar

[2] T. Kakui, H. Kamiya, Effect of Sodium Aromatic Sulfonate Group in Anionic Polymer Dispersant on the Viscosity of Coal-Water Mixtures, Energy Fuels 18 (2004), 652-658.

DOI: 10.1021/ef030154a

Google Scholar

[3] D. Das, S. Panigrahi, P.K. Misra, and A. Nayak, Effect of Organized Assemblies. Part 4. Formulation of Highly Concentrated Coal Water Slurry Using a Natural Surfactant, Energy Fuels 22 (2008), 1865–1872.

DOI: 10.1021/ef7006563

Google Scholar

[4] W. He, C.S. Park, J.M. Norbeck, Rheological Study of Comingled Biomass and Coal Slurries with Hydrothermal Pretreatment, Energy Fuels, 23 (2009) 4763-4767.

DOI: 10.1021/ef9000852

Google Scholar

[5] D. Debadutta, D. Uma, N. Amalendu, and P.K. Misra, Surface Engineering of Low Rank Indian Coals by Starch-Based Additives for the Formulation of Concentrated Coal-Water Slurry, Energy Fuels. 24 (2010), 1260-1268.

DOI: 10.1021/ef900921c

Google Scholar

[6] F. Boylu, H. Dincer, G. Atesok, Effect of coal particle size distribution, volume fraction and rank on the rheology of coal-water slurries, Fuel Proces. Technol. 85 (2004) 241-250.

DOI: 10.1016/s0378-3820(03)00198-x

Google Scholar

[7] Z.J. Zhou, X. Li, J. M Liang, J. Z Liu, J.H. Zhou, and K.F. Cen, Surface Coating Improves Coal-Water Slurry Formation of Shangwan Coal, Energy Fuels. 25 (2011), 3590–3597.

DOI: 10.1021/ef200529h

Google Scholar