Dissolution Behaviour and the Solution Property of Cellulose in NaOH/Urea/Thiourea Aqueous Solvent

Huan Li; Hai Feng Li; Xuan Zhong; Magdi E. Gibril; Xin Da Li; Yue Zhang; Ke Qing Han; Mu Huo Yu

doi:10.4028/www.scientific.net/AMR.581-582.73

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 581-582Dissolution Behaviour and the Solution Property of...

Dissolution Behaviour and the Solution Property of Cellulose in NaOH/Urea/Thiourea Aqueous Solvent

Abstract:

Cellulose swelling and dissolving, rheological properties, crystallinity, gel Abstract. Untreated cellulose was directly and quickly dissolved in NaOH/thiourea/urea aqueous solvent at a 9/3/5/83 composition and pre-cooled at (-10 to +2)°C, and at a high shear force with 3500rpm agitating speed. The dissolving process was investigated by polarization microscope, XRD and rheometer. The result revealed that cellulose crystal forms was changed from cellulose I to cellulose II after dissolving and the crystallinity decreased. Moreover, the gel forming of cellulose has an obvious relationship with cellulose concentration and it’s easy to form gel when the cellulose concentration was above 8wt%.

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Periodical:

Advanced Materials Research (Volumes 581-582)

Pages:

73-76

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.581-582.73

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Online since:

October 2012

Authors:

Huan Li, Hai Feng Li, Xuan Zhong, Magdi E. Gibril, Xin Da Li, Yue Zhang, Ke Qing Han, Mu Huo Yu

Keywords:

Cellulose Dissolving, Cellulose Swelling, Crystallinity, Gel, Rheological Property

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References

[1] Yuan Mao, Lina Zhang, Jie Ca, Jinping Zhou, Tetsuo Kondo. Eeffects of Coagulation Conditions on Properties of Multifilament Fibers Based on Dissolution of Cellulose in NaOH/Urea Aqueous Solution. ［J］Ind. Eng. Chem. Res. 2008，47，8676-8683.

DOI: 10.1021/ie800833w

Google Scholar

[2] Jie Cai, Lina Zhang. Rapid Dissolution of Cellulose in LiOH/Urea andNaOH/Urea Aqueous Solutions. [J] Macromol. Biosci. 2005, 5, 539–548.

DOI: 10.1002/mabi.200400222

Google Scholar

[3] K. Kamide, K. Okajama, T. Matsui, K. Kowsaka. [J] Polym. 1984, 12, 857.

Google Scholar

[4] K. Kowsaka, K. Kamide, K. Okajima. International symposium on new functionalisation developments in cellulosics and wood. [J] Cellusion 88, Kyoto, Japan, (1988).

Google Scholar

[5] T. Yamashiki, T. Matsui, M. Saitoh, K. Okajima, K. Kamide, T. Sawada. International symposium on new functionalisation developments in cellulosics and wood. [J] Cellusion 88, Kyoto, Japan, (1988).

Google Scholar

[6] Zhou J．，Zhang L．［J］ Polym．，2000，32( 10) : 866 870.

Google Scholar

[7] Shuai Zhang, Fa-Xue Li, Jian-yong Yu , You-Lo Hsieh. Dissolution behaviour and solubility of cellulose in NaOH complex solution. [J] Carbohydrate Polymers 81 (2010) 668–674.

DOI: 10.1016/j.carbpol.2010.03.029

Google Scholar

[8] Xuming Chen , Christian Burger, Dufei Fang , Dong Ruan , Lina Zhang , Benjamin S. Hsiao, Benjamin Chu . X-ray studies of regenerated cellulose ﬁbers wet spun from cottonlinter pulp in NaOH/thiourea aqueous solutions. [J] Polymer 47 (2006).

DOI: 10.1016/j.polymer.2006.02.044

Google Scholar

[9] Zha Chun -xi , Jin Hua -jin, Gu Li –xia. Dissolution and Solution Properties of Cellulose in NaOH /Thiourea /Urea Aqueous Solution. [J] Journal of Donghua University (Natural Science) Vol. 34 (2008) 20-43.

DOI: 10.1016/j.carres.2006.12.023

Google Scholar