Determining the Engine Oil’s TBN by Semi-Derivative Voltammetry

Article Preview

Abstract:

A new method was proposed for determining total base numbers (TBN) of engine oils with semi-derivative Voltammetry. This method uses acetone containing hydrochloric acid as neutralization agent for titrating TBN, the remained hydrochloric acid reacts with insoluble substances, the insoluble substances are transformed into soluble and electro-active ones in acetone. Through determining the concentration of electro-active substances in the solution, oil’s TBN could be evaluated accurately. The experimental results had shown the method is simple, rapid environmentally-friendly, and could be used at-site.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 608-609)

Pages:

1437-1440

Citation:

Online since:

December 2012

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] J R Barnes. Importance of Railroad Diesel Engine Oil TBN and its Relevance to LMOA Generation 5 for analysis of Lubricants Using Non-Hazardous Solvents[R]. Dexsil Corporation, www.dexsil.com,One Hamden Park Drive, Hamden, CT 06517.

Google Scholar

[2] Stephen Finch. Evaluation of a Field Test Method for Total Base Number Determination in Lube Oils[R]. Dexsil Corporation, www.dexsil.com, One Hamden Park Drive, Hamden, CT 06517.

Google Scholar

[3] R E Kauffman. Rapid, Portable Voltammetric Techniques for Performing Antioxidants, Total Acid Number and Total Base Number Measurements [J]. Lubrication Engineering, 1998, 54(1), 39-45.

Google Scholar

[4] Shi Yonggang, Ma Yan, Li Zicun. Determination of Total Base Number of Engine Lubricating Oils by Cycle Voltammetry [J]. Chemical Engineering of Oil & Gas,2004,33(1), 56.

Google Scholar

[5] Shi Yonggang. Rapid Determination of Antioxidants, Total Acid Number and Total Base Number in Lubricants [J]. Physical Testing and Chemical Analysis, Part B: Chemical Analysis,2002,38(12), 611.

Google Scholar