Paper Titles

Dynamic Energy Absorption of Filament Winding Conical Composite with Different Orientation Angle and Low Velocity
p.241

Deformation Modeling of an FGM Plate under External Force
p.246

Hydrophilic Functionalized Bi-Layered Polymer Magnetic Core/Shell: Preparation and Characterization
p.254

Graphene Basics and Applications
p.259

Poly(3-hydroxybutyrate) - Organo Modified Montmorillonite Nanohybrid; Preparation and Characterization
p.263

Polycaprolactone Fiber Bundles Prepared by Self-Bundling Electrospinning
p.271

The Study on Preparation of Kaolin-Acrylic Super Absorbent Polymer and its Internal Curing Effect in the Hydration Procedure of Cement Materials
p.276

Electron Microstructure Study of Z_rO₂-C_aO-Al₂O₃ Ceramics Materials
p.280

Microstructure and Electrical Properties of the (Ba_1-xCa_x)(Ti_0.96Zr_0.02Sn_0.02)O₃ Ceramics
p.283

HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 622-623Poly(3-hydroxybutyrate) - Organo Modified...

Poly(3-hydroxybutyrate) - Organo Modified Montmorillonite Nanohybrid; Preparation and Characterization

Article Preview

Abstract:

Nano-biohybrid, based on biodegradable polyester, poly (3-hydroxybutyrate) (PHB), and a commercial organo modified montmorillonite (MMT), were prepared by solvent casting technique. Morphology and non-isothermal degradation of PHB and PHB/MMT hybrids were characterized by POM and TG-DTG technique. In the composite materials, an increase MMT loading in the PHB decreased the onset temperature (Tonset) of thermal degradation, while it achieved higher values upon increasing the heating rate. Kissinger plots deduced a trend of the degradation activation energy, Ed, which was related to the agglomeration of MMT. The thermal degradation rate constant, k, was related to the MMT loading in PHB. X-ray diffraction analysis confirmed the expansion of MMT silicate layers.

You might also be interested in these eBooks

Manufacturing Science and Technology III

Info:

Periodical:

Advanced Materials Research (Volumes 622-623)

Pages:

263-270

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.622-623.263

Citation:

Cite this paper

Online since:

December 2012

Authors:

Ali Salehabadi, Mohamad Abu Bakar

Keywords:

Kinetic, Kissinger, Modified Nanoclay, Morpholoy, Poly(3-Hydroxybutyrate), Thermal Decomposition

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] P.A. Holmes: Physics in Technology: Vol. 16 (1985), P. 32-36.

[2] P.J.B.C. Birley , J. Briddon , K.E. Sykes, P.A. Barker and S.J. Organ, Journal of Materials Science: Vol. 30 (1995), P. 633-638.

[3] C. Vogel and H.W. Siesler, Macromolecular Symposia: Vol. 265 (2008), P. 183-194.

[4] H.K. Lee, J. Ismail, H.W. Kammer and M.A. Bakar, Polymer: Vol. 95 (2004), P. 113-129.

[5] P. Bordes, E. Pollet and L. Averous, Progress in Polymer Science: Vol. 34 (2009), P. 125-155.

[6] C. Baillie, Green Composites: Polymer Composites and Environment, 1st Ed., Ontario, Queen, s University, (2005).

[7] L.A. Utracki, Clay-Containing Polymeric Nanocomposites, (2004).

[8] F. Uddin, Metallurgical and Materials Transactions A: Vol. 39 (2008), P. 2804-2814.

[9] S. Tjong, Materials Science and Engineering Reports: Vol. 53 (2006), P. 73-197.

[10] A. Botana, M. Mollo, P. Eisenberg and R.M. Torres Sanchez, Applied Clay Science: Vol. 47 (2010), P. 263-270.

DOI: 10.1016/j.clay.2009.11.001

[11] X. Fu, S. Qutubuddin, Polymer: Vol. 42 (2001), P. 807-813.

[12] A. Leszczy, J. Njuguna, K. Pielichowski and J.R. Banerjee, Thermochimica Acta: Vol. 454 (2007), P. 1-22.

[13] J.A. Howarter and J.P. Youngblood, Macromolecules: Vol. 40 (2007), P. 1128-1132.

[14] A.K. Manna, D.K. Tripathy, P.P. De, S.K. De, M.K. Chatterjee and D.G. Peiffer, Journal of Applied Polymer Science: Vol. 72 (1999), P. 1895-(1903).

[15] A.K. Barick and D.K. Tripathy, Journal of Applied Polymer Science: Vol. 33 (2010), P. 639-654.

[16] Q. Yuan, S. Awate and R. Misra, European Polymer Journal: Vol. 42 (2006), P. 1994-(2003).

[17] S.Y. Yeo, W.L. Tan, M. Abu Bakar and J. Ismail, Polymer Degradation and Stability: Vol. 95 (2010), P. 1299-1304.

DOI: 10.1016/j.polymdegradstab.2010.02.025

[18] P. Bordes, E. Hablot, E. Pollet and L. Avérous, Polymer Degradation and Stability: Vol. 94 (2009), P. 789-796.

DOI: 10.1016/j.polymdegradstab.2009.01.027

[19] J. F.W. Billmeyer, Text Book of Polymer Science, Third Ed., John Wiley, NEW YORK, (1984).

[20] O.E. Farrance, R. A. L. Jones and J.K. Hobbs, Polymer: Vol. 50 (2009), P. 3730-3738.

[21] T. Jiang, Y.H. Wang, J.T. Yeh and Z.Q. Fan, European Polymer Journal: Vol. 41 (2005), P. 459-466.

[22] C. Zhijiang and Y. Guang, Materials Letters: Vol. 65 (2011), P. 182-184.

[23] R. A. Vaia and E.P. Giannelis, Macromolecules: Vol. 30 (1997), P. 8000-8009.

[24] P. Bordes, E. Pollet, S. Bourbigot and L. Avérous, Macromolecular Chemistry and Physics: Vol. 209 (2008), P. 1473-1484.

[25] D.A.D. Amico, L.B. Manfredi, V.P. Cyras, N.D. Mar, J.B. Justo and M. Plata, Journal of Applied Polymer Science: Vol. 123 (2011), P. 200-208.

[26] A. Botana, M. Mollo, P. Eisenberg and R.M. Torres Sanchez, Applied Clay Science: Vol. 47 (2010), P. 263-270.

DOI: 10.1016/j.clay.2009.11.001

[27] J.M. Cervantes-Uc, J.V. Cauich-Rodríguez, H. Vázquez-Torres, L.F. Garfias-Mesías and D.R. Paul, Thermochimica Acta: Vol. 457 (2007), P. 92-102.

DOI: 10.1016/j.tca.2007.03.008