Preparation and Release Behavior of Polyelectrolyte Microcapsules

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Hybrid calcium carbonate (CaCO3)/poly(styrene sulfonate) (PSS) particle, as a template, was synthesized using colloidal crystallization with the presence of nitrate tetrahydrate (Ca(NO3)2•4H2O), sodium carbonate (Na2CO3) and PSS. Microcapsule was prepared by template-assisted layer-by-layer (LbL) technology in solutions of two oppositely charged polyelectrolytes, poly(styrenesulfonate) (PSS) and poly(allylamine hydrochloride) (PAH) alternately, followed by dissolving the template with disodium ethylenediaminetetraacetate (EDTA). The release behavior of rhodamine B (RhB) from the microcapsules was examined and the rates of release at different pH were studied.

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December 2012

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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[1] Matthieu F. Bédard, Bruno G. De Geest, Andre G. Skirtach, et al. Polymeric microcapsules with light responsive properties for encapsulation and release [J]. Advances in Colloid and Interface Science, 2010, 158: 2-14.

DOI: 10.1016/j.cis.2009.07.007

Google Scholar

[2] Hyukjin Lee, Yongho Jeong, Tae Gwan Park.. Shell Cross-Linked Hyaluronic Acid/Polylysine Layer-by-Layer Polyelectrolyte Microcapsules Prepared by Removal of Reducible Hyaluronic Acid Microgel Cores [J]. Biomacromolecules, 2007, 8: 3705-3711.

DOI: 10.1021/bm700854j

Google Scholar

[3] Mary M. Caruso, Douglas A. Davis, Qilong Shen, et al. Mechanically-Induced Chemical Changes in Polymeric Materials [J]. Chem. Rev., 2009, 109: 5755-5798.

DOI: 10.1021/cr9001353

Google Scholar

[4] Francesca Cavalieri, Almar Postma, Lillian Lee, et al. Assembly and Functionalization of DNA-Polymer Microcapsules [J]. ACS Nano, 2009, 3 (1): 234-239.

DOI: 10.1021/nn800705m

Google Scholar

[5] Mojgan Zandi, Seyed Ali H ashemi, Payam Aminayi. Microencapsulation of Disperse Dye Particles with Nano Film Coating Through Layer-by-layer Technique [J]. Journal of Applied Polymer Science, 2011, 119: 586-594.

DOI: 10.1002/app.32674

Google Scholar

[6] Lei YB, Hurst JK. Photoregulated potassium ion permeation through dihexadecyl phosphate bilayers containing azobenzene and stilbene surfactants [J].Langmuir, 1999, 15: 3424-3429.

DOI: 10.1021/la981223u

Google Scholar

[7] Alexander W. Scott, Betty M. Tyler, Byron C. Masi, et al. Intracranial microcapsule drug delivery device for the treatment of an experimental gliosarcoma model[J]. [Quick Edit]Biomaterials, 2011, 32: 2532-2539.

DOI: 10.1016/j.biomaterials.2010.12.020

Google Scholar

[8] Jian Zhang, Yi Fu, Feng Jiang, et al. Metal Nanoshell -Capsule for Light-Driven Release of a Small Molecule[J]. J. Phys. Chem. C, 2010, 114:7653-7659.

DOI: 10.1021/jp911537w

Google Scholar

[9] Uttam Manna, Satish Patil. Dual Drug Delivery Microcapsules via Layer-by-Layer Self-Assembly[J]. Langmuir, 2009, 25(18): 10515-10522.

DOI: 10.1021/la901243m

Google Scholar

[10] Khek-Khiang Chia, Robert E. Cohen, Michael F. Rubner. Amine-Rich Polyelectrolyte Multilayer Nanoreactors for in Situ Gold Nanoparticle Synthesis[J]. Chem. Mater., 2008, 20: 6756–6763.

DOI: 10.1021/cm802166s

Google Scholar

[11] Shupeng She, Chunxiu Xu, Xuefeng Yin, et al. Shape Deformation and Recovery of Multilayer Microcapsules after Being Squeezed through a Microchannel[J]. Langmuir, 2012, 28: 5010− 5016.

DOI: 10.1021/la3003299

Google Scholar

[12] Benjamin Thierry, Lucie Zimmer, Scott McNiven, et al. Electrostatic Self-Assembly of PEG Copolymers onto Porous Silica Nanoparticles[J]. Langmuir, 2008, 24: 8143-8150.

DOI: 10.1021/la8007206

Google Scholar

[13] Alberto Diaspro, Daniela Silvano, Silke Krol et al. Single Living Cell Encapsulation in Nano-organized Polyelectrolyte Shells[J]. Langmuir, 2002, 18: 5047-5050.

DOI: 10.1021/la025646e

Google Scholar

[14] Alexei A. Antipov, Dmitry Shchukin, Yuri Fedutik,et al. Carbonate microparticles for hollow polyelectrolyte capsules fabrication[J]. Colloids and Surfaces A: 2003, 224: 175-183.

DOI: 10.1016/s0927-7757(03)00195-x

Google Scholar

[15] A. J. Chung, M. F. Rubner. Methods of Loading and Releasing Low Molecular Weight Cationic Molecules in Weak Polyelectrolyte Multilayer Films[J]. Langmuir, 2002, 18: 1176-1183.

DOI: 10.1021/la010873m

Google Scholar

[16] Bruno G. De Geest, Niek N. Sanders, Gleb B, et al. SukhorukovRelease mechanisms for polyelectrolyte capsules[J]. Chem. Soc. Rev., 2007, 36: 636–649.

DOI: 10.1039/b600460c

Google Scholar

[17] Christophe De´jugnat, Gleb B. Sukhorukov. pH-Responsive Properties of Hollow Polyelectrolyte Microcapsules Templated on Various Cores[J]. Langmuir, 2004, 20: 7265-7269

DOI: 10.1021/la049706n

Google Scholar