Effect of an Anionic Polyelectrolyte Adsorption on the Colloidal Stability of Aqueous 3Y-TZP Suspensions

You Qiang Chen; Xin Ni Zhang; Qing Shan Kong; Yan Zhi Xia

doi:10.4028/www.scientific.net/AMR.629.317

Paper Titles

BaTiO₃Nanopowders Hydrothermally Synthesized Using H₂Ti₃O₇ Nanotubes and Nanorods
p.292

Scale Coefficient, Length, Mode and Radius Effect on Critical Axial Compressed Buckling Load of Carbon Nanotubes via Nonlocal Continuum Model
p.296

Synthesis of Various Nanostructures ZnO and its Applications for Gas Sensors
p.302

Electric Polarization Characteristic and Equivalent Circuit of the Pb(Zr_0.95Ti_0.05)O₃ Nanoceramics
p.309

Effect of an Anionic Polyelectrolyte Adsorption on the Colloidal Stability of Aqueous 3Y-TZP Suspensions
p.317

Catalytic Performance of Dimethyl Ether Combustion over La-Ce-Cu/Al₂O₃ Catalysts
p.322

A Thermometric Analysis for an Explosion Accident in a Nitromethane Rectification Process
p.327

Dye-Sensitized Solar Cells Based on Three-Dimensional Web-Like Structure Anodes
p.332

Developing of a Lubricant Oil for the Ship Gas Turbine of Reducer
p.339

HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 629Effect of an Anionic Polyelectrolyte Adsorption on...

Effect of an Anionic Polyelectrolyte Adsorption on the Colloidal Stability of Aqueous 3Y-TZP Suspensions

Abstract:

The effects of an anionic polyelectrolyte on the dispersion of 3Y-TZP suspensions in aqueous medium have been systematically investigated. The results of rheological experiments show that at CD = 0.5 wt% (CD : dispersant concentration), the dispersant could afford well-dispersed 3Y-TZP suspensions over a wider range of solids loading, owing to the stronger electrostatic repulsion between particles resulting from the monolayer coverage of the particle. But as CD ≤ 0.5 wt% or CD ≥0.5 wt%, the stable 3Y-TZP suspensions can only be achieved at a relatively lower solids loading, which are ascribed to the reduced repulsion barrier between particles owing to the lower ζ values of particles and the higher ionic strength in the system, respectively.

You might also be interested in these eBooks

Material Sciences and Manufacturing Technology

View Preview

Info:

Periodical:

Advanced Materials Research (Volume 629)

Pages:

317-321

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.629.317

Citation:

Cite this paper

Online since:

December 2012

Authors:

You Qiang Chen, Xin Ni Zhang, Qing Shan Kong, Yan Zhi Xia

Keywords:

3Y-TZP, Anionic Polyelectrolyte, Rheology, Zeta-Potential

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

References

[1] J. A. Lewis. Colloidal Processing of Ceramics.J. Am. Ceram. Soc. 2000; 83: 2341–59.

Google Scholar

[2] M. Montero, T. Molina, M. Szafran, R. Moreno and M. I. Nieto. Alumina porous nanomaterials obtained by colloidalprocessing using d-fructose as dispersant and porosity promoter. Ceram. Int. 2012; 38: 2779–84.

DOI: 10.1016/j.ceramint.2011.11.048

Google Scholar

[3] A. Natoli, A. Cabeza, Á. G. De La Torre, M. A. G. Aranda and I. Santacruz. Colloidal Processing of Macroporous TiO2 Materials for Photocatalytic Water Treatment. J. Am. Ceram. Soc. 2012: 95: 502–08.

DOI: 10.1111/j.1551-2916.2011.04883.x

Google Scholar

[4] D. Guo,K. Cai L.T. Li, and Z.L. Gui. Application of Gelcasting to the Fabrication of Piezoelectric Ceramic Parts, J. Eur. Ceram. 2003; 23: 1131-37.

DOI: 10.1016/s0955-2219(02)00279-0

Google Scholar

[5] V. A. Hackley. Colloidal Processing of Silicon Nitride with Poly(acrylic acid): I, Adsorption and Electrostatic Interactions. J. Am. Ceram. Soc. 1997; 80: 2315-25.

DOI: 10.1111/j.1151-2916.1997.tb03122.x

Google Scholar

[6] H. Guldberg-Pedersen and L. Bergström. Forces between Zirconia Surfaces in Poly(acrylic acid)Solutions. J. Am. Ceram. Soc. 1999; 82: 1137-4.

DOI: 10.1111/j.1151-2916.1999.tb01887.x

Google Scholar

[7] C.G. de kruif. Hydrodynamics of Dispersed Media. Edited by J.P. Hulin, A.M. Cazab at, E. Guyon, and F. Carmona. Elsevier Science, Amsterdam, The Netherlands, 1990, pp.79-85.

Google Scholar