Dye-Sensitized Solar Cells Based on Three-Dimensional Web-Like Structure Anodes

Article Preview

Abstract:

TiO2 films with three-dimensional web-like structure have been prepared by the photo polymerization-induced phase separation method (PIPS). Scanning electron microscopy and X-ray diffraction were used to characterize the as-prepared TiO2 films. The results showed that the film texture could be tuned by changing the composition of the precursor solution. The TiO2 film with web-like structure exhibited high photocatalytic activity for the degradation of methylene blue (MB) dye. The as-prepared films were used as the photo-anodes in dye-sensitized solar cells (DSCs). The photoelectric conversion efficiency of the DSCs was significantly enhanced by changing the POGTA/TTB in the precursor solution. Because of the increased dye adsorption active sites and efficient electron transport in the TiO2 anode film, a photoelectric conversion efficiency of 3.015% was obtained.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

332-338

Citation:

Online since:

December 2012

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] O'Regan B, Gratzel M. A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films. J Nature 1991; 353: 737-740.

DOI: 10.1038/353737a0

Google Scholar

[2] A. Sreekumaran Nair, Rajan Jose, Yang Shengyuan, Seeram Ramakrishna. A simple recipe for an efficient TiO2 nanofiber-based dye-sensitized solar cell. J Journal of Colloid and Interface Science 2011; 353: 39-45.

DOI: 10.1016/j.jcis.2010.09.042

Google Scholar

[3] Seigo Ito, Takurou N. Murakami, Pascal Comte, Paul Liska, Carole Grätzel, Mohammad K. Nazeeruddin. Fabrication of thin film dye sensitized solar cells with solar to electric power conversion efficiency over 10%. J Thin Solid Films 2008; 516: 4613–9.

DOI: 10.1016/j.tsf.2007.05.090

Google Scholar

[4] Michael Grätzel. Dye-sensitized solar cells. J Journal of Photochemistry and Photobiology 2003; 4: 145-153.

Google Scholar

[5] Nak CheonJeong, OmarK. Farha, Joseph T. Hupp. A Convenient Route to High Area, Nanoparticulate TiO2 Photoelectrodes Suitable for High-Efficiency Energy Conversion in Dye-Sensitized Solar Cells. J Langmuir 2011; 27(5): 1996-9.

DOI: 10.1021/la104297s

Google Scholar

[6] Jing Zhang, Qian Xu, Zhaochi Feng, Meijun Li, Can Li. Importance of the relationship between surface phases and photocatalytic activity of TiO2. J Angew. Chem. Int. Ed. 2008; 47: 1766–9.

DOI: 10.1002/anie.200704788

Google Scholar

[7] Frederic Sauvage, Dehong Chen, Pascal Comte, Fuzhi Huang, Leo-Philipp Heiniger, Yi-Bing Cheng et al. Dye-Sensitized Solar Cells Employing a Single Film of Mesoporous TiO2 Beads Achieve Power Conversion Efficiencies Over 10%. J American Chemical Society 2010; 4(8): 4420-5.

DOI: 10.1021/nn1010396

Google Scholar

[8] Hao Pan, Jieshu Qian, Ang Yu, Meigui Xu, Luo Tu, Qingli Chai et al. TiO2 Wedgy Nanotubes Array Flims for Photovoltaic Enhancement. J Applied Surface Science 2011; 257: 5059-5063.

DOI: 10.1016/j.apsusc.2011.01.021

Google Scholar

[9] Qi Pang, Limin Leng, Lijuan Zhao, Liya Zhou, Chunjie Liang, Yuwei Lan. Dye sensitized solar cells using freestanding TiO2 nanotube arrays on FTO substrate as photoanode. J Materials Chemistry and Physics 2011; 125: 612-6.

DOI: 10.1016/j.matchemphys.2010.10.009

Google Scholar

[10] Jianxi Yao, Hongxing Tian, Masahide Takahashi, Toshinobu Yoko. Fabrication and characterization of macroporous TiO2 films by photo polymerization-induced phase separation method. J Materials Letters 2010; 64: 2049-(2052).

DOI: 10.1016/j.matlet.2010.06.064

Google Scholar

[11] Jianxi Yao, Masahide Takahashi, Toshinobu Yoko. Controlled preparation of macroporous TiO2 films by photopolymerization-induced phase separation method and their photocatalytic p erformance. J Thin Solid Films 2009; 517: 6479–6485.

DOI: 10.1016/j.tsf.2009.03.214

Google Scholar

[12] Guangxiu Cao, Yaogang Li, Qinghong Zhang, Hongzhi Wang. Hierarchical Porous, Self-Supporting La- and F-Codoped TiO2 with High Durability for Continuous-Flow Visible Light Photocatalysis. J American Ceramic Society 2010; 93(5): 1252–5.

DOI: 10.1111/j.1551-2916.2009.03552.x

Google Scholar

[13] Kaisheng Xia, Dean Ferguson, Yahia Djaoued, Jacques Robichaud, Nadéjda Tchoukanova, Ralf Brüning et al. Template-free synthesis and photocatalytic activity of hierarchical porous titania with controlled texture and crystalline structure. J Applied Catalysis A: General 2010; 387: 231–241.

DOI: 10.1016/j.apcata.2010.08.041

Google Scholar

[14] Inyoung Shin, Hyunwoong Seo, Min-Kyu Son, Jin-Kyoung Kim, K. Prabakar, Hee-Je Kim. Analysis of TiO2 thickness effect on characteristic of a dye-sensitized solar cell by using electrochemical impedance spectroscopy. J Current Applied Physics 2010; 10: S422–S424.

DOI: 10.1016/j.cap.2009.12.039

Google Scholar

[15] Ho-Gyeong Yun, Jong Hyeok Park, Byeong-Soo Bae, Man Gu Kang. Dye-sensitized solar cells with TiO2 nano-particles on TiO2 nano-tube-grown Ti substrates. J Journal of Materials Chemistry 2011; 21: 3558–3561.

DOI: 10.1039/c0jm04210b

Google Scholar

[16] Rui Liu, Wein-Duo Yang, Liang-Sheng Qiang. Enhanced efficiency for dye-sensitized solar cells using a surface-treated photo-anode. J Journal of Power Sources 2012; 199: 418–425.

DOI: 10.1016/j.jpowsour.2011.10.072

Google Scholar

[17] C. Charbonneau, R. Gauvin, G. P. Demopoulos. Aqueous Solution Synthesis of Crystalline Anatase Nanocolloids for the Fabrication of DSC Photoanodes. J Journal of The Electrochemical Society 2011; 158(3): H224-H231.

DOI: 10.1149/1.3529238

Google Scholar