Catalytic Methoxycarbonylation of 1,6-Hexamethylenediamine with Methyl Carbamate to Dimethylhexane-1,6-Dicarbamate

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Abstract:

A series of metal oxides were employed as catalysts for the synthesis of dimethylhexane -1,6-dicarbamate(HDC) from 1,6-hexamethylenediamine(HDA) and methyl carbonate(MC). Lead dioxide showed excellent catalytic activity, 100% HDA conversion and 93% HDC yield could be achieved at 463K for 6h. The effects of reaction temperature, reaction time and catalyst amount on the yield of HDC were investigated in details.

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Periodical:

Advanced Materials Research (Volumes 634-638)

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490-493

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January 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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