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The Direct Carboxylation of Terminal Alkynes with Carbon Dioxide Using Copper-Conjugated Microporous Polymer as Catalyst

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Abstract:

A Cu-conjugated microporous polymer catalyst (CMP-Cu) was designed and prepared via Sonogashira-Hagihara cross-coupling of 3,8-dibromo-1,10-phenanthroline with 1,3,5-triethyny benzene in toluene. The CMP-Cu showed a catalytic activity for direct carboxylation of terminal alkynes with CO2 in the presence of K2CO3/Cs2CO3 at mild conditions. Several propiolic acids (such as 3-phenylpropiolic acid, 3-(4-nitrophenyl)propiolic acid and 4,4-dimethyl-2-pentynoic acid) have been prepared in a simple and feasible method at room temperature and atmospheric pressure. This catalyst is attractive for CO2 transformation.

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Periodical:

Advanced Materials Research (Volumes 634-638)

Pages:

612-615

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.634-638.612

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Online since:

January 2013

Authors:

Yong Xie, Bi Feng He, Nian Yu Huang, Wei Qiao Deng

Keywords:

Carbon Dioxide Transformation, Carboxyation, Catalyst, Conjugated Microporous Polymer, Organic Synthesis

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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