Esterification of 5-Norbornene-2,3-Dicarboxylic Anhydride under Titanium Catalyst

Sung Ho Park; Jun Seong Park; Tae Won Ko; Yong Sung Park; Je Wan Woo

doi:10.4028/www.scientific.net/AMR.634-638.642

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 634-638Esterification of 5-Norbornene-2,3-Dicarboxylic...

Esterification of 5-Norbornene-2,3-Dicarboxylic Anhydride under Titanium Catalyst

Abstract:

Norbornene dicarboxylate was synthesized through esterification under titanium catalyst. The alcohols are 2-ethyl-1-hexanol, n-octanol, 3,5,5-trimethyl-1-hexanol, and n-decanol. The Structures of compounds were identified by 1H-NMR, and then components were identified by high performance liquid chromatography (HPLC). The yield and purity was over 90 % and 95 %, and color of compounds was colorless or light yellow. The maleate as a by-product was occured by the retro Diels-Alder reaction.

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Periodical:

Advanced Materials Research (Volumes 634-638)

Pages:

642-646

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.634-638.642

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Online since:

January 2013

Authors:

Sung Ho Park, Jun Seong Park, Tae Won Ko, Yong Sung Park, Je Wan Woo

Keywords:

Diels-Alder Reaction, Esterification, Norbornene Derivatives, Retro Diels-Alder Reaction, Titanium(IV) Isopropoxide

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