Esterification of 5-Norbornene-2,3-Dicarboxylic Anhydride under Titanium Catalyst

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Abstract:

Norbornene dicarboxylate was synthesized through esterification under titanium catalyst. The alcohols are 2-ethyl-1-hexanol, n-octanol, 3,5,5-trimethyl-1-hexanol, and n-decanol. The Structures of compounds were identified by 1H-NMR, and then components were identified by high performance liquid chromatography (HPLC). The yield and purity was over 90 % and 95 %, and color of compounds was colorless or light yellow. The maleate as a by-product was occured by the retro Diels-Alder reaction.

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Advanced Materials Research (Volumes 634-638)

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642-646

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January 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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[1] D.A. Evans and J.S. Johnson, in: Comprehensive Asymmetric Catalysis I-III, edited by E.N. Jacobsen, A. Pfaltz, H. Yamamoto, chapter, 33. 1, isites. harvard. edu, Springer-Verlag Berlin Heidelberg (1999).

Google Scholar

[2] M. Arabi, M.M. Amini, M. Abedini, A. Nemati and M. Alzadeh: Jonal of Molecular Catalysis A: Chemical, Vol. 200 (2003), pp.105-110.

Google Scholar

[3] J. Skrzypek, J.Z. Sadlowski, M. Lachowska and M. Turzanski: Chemical Engineering and Processing, vol. 33 (1994), 413-418.

Google Scholar

[4] H.E. Hoydonckx, D.E. De Vos, S.A. Chavan and P.A. Jacobs: Topics in Catalysis, vol. 27 (2004), pp.1-4.

Google Scholar

[5] J. Ridland, I.W. Hepplewhite and B.S. Jolly, U.S. Patent 5, 866, 710 (1999).

Google Scholar

[6] F.X. Werber, U.S. Patent 3056818 (1962).

Google Scholar

[7] D. Birney, T.K. Lim, J.H.P. Koh, T.R. Pool and J.M. White: J. Am. Chem. Soc., Vol. 124 (2002), pp.5091-5099.

Google Scholar

[8] K.H. Yoo, J.C. Ryu: j. of Korean Oil Chemists' Soc., Vol. 24 (2007), pp.211-218.

Google Scholar

[9] D. Craig: J. Am. Chem. Soc., Vol. 73 (1951), p.4889.

Google Scholar

[10] H. Kwart and K. King: Chemical Reviews, ACS Publications (1968).

Google Scholar