Research of Copolymerization Kinetics of CO and C2H4 Catalysed by Palladium

Wen Wei; Liang Chen; Shi Ling Zhang; Jing Deng; Jia Yao Du; Ling Gao

doi:10.4028/www.scientific.net/AMR.634-638.701

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 634-638Research of Copolymerization Kinetics of CO and...

Research of Copolymerization Kinetics of CO and C₂H₄ Catalysed by Palladium

Abstract:

A dynamical behavior about preparation polyketone from Carbon monoxide and ethene alternately copolymerization in methanol by catalyst cantained palladium acetate and DPPP was detailed represented in this paper. The synthesis mechanism of PK has been studied detailed, and a kinetic model equation is established, and the model parameter was determination. The product(PK) is not strictly alternating copolymerization, and their molecule chain cantained main -(CH₂CH₂CO)n-, and presence of a small amount of -CH₂CH₂CH₂CH₂CO-. The results showed that dynamical equation of the CO/C₂H₂ copolymerization to PK have corresponded with experiment data very well. In other words the kinetic equation of CO/C₂H₂ alternate copolymerization by Pd(AeO)/DPPP catalyst can used to describe their reaction behavior.

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Periodical:

Advanced Materials Research (Volumes 634-638)

Pages:

701-707

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.634-638.701

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Online since:

January 2013

Authors:

Wen Wei, Liang Chen, Shi Ling Zhang, Jing Deng, Jia Yao Du, Ling Gao

Keywords:

Carbon Monoxide, Copolymerization, Dynamic, Ethene, Palladium

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References

[1] E. Drent, H.M. Brudzelaar. Chemistry Reviews. 96 (1996) 663~681.

Google Scholar

[2] G.W. Coates, Chemistry Reviews. 100 (2000) 1223.

Google Scholar

[3] G.P. Belov, E.V. Novikova, Polyketones as alternating copolymers of carbon monoxide, Russ. Chem. Rev. 73 (2004) 267~291.

DOI: 10.1070/rc2004v073n03abeh000840

Google Scholar

[4] Gregory GHlatky. Single-site catalysts for olefin polymerization：Annual review for 1997 [J]. Coord Chern Rev，2000，199：235~329.

Google Scholar

[5] He-Kuan Luo, Da-Gang Li. Studies on new palladium(II) catalyst system for copolymerization of CO with ethylene: Journal of Molecular Catalysis A: Chemical 171 (2001) 23~31.

DOI: 10.1016/s1381-1169(00)00148-5

Google Scholar

[6] Andrea, Vavasori. Gianni, Cavinato. Luigi, Toniolo. Carbon monoxide–ethylene copolymerization catalyzed by a Pd(OAc)2/dppp/formic acid system [dppp= 1, 3-bis(diphenylphosphino) propane]: Journal of Molecular Catalysis A: Chemical 191 (2003).

DOI: 10.1016/s1381-1169(02)00174-7

Google Scholar

[7] Liping Zou, Liang Chen, Yongcheng Chen. Natural Gas Chemical Industry, 2007, 32(1): 64~68. In Chinese.

Google Scholar

[8] Yongcheng Chen, Liang Chen, Liping Zou. Natural Gas Chemical Industry, 2007, 32(3): 22~25. In Chinese.

Google Scholar

[9] Olga M. Chukanova, Kirill A. Alpherov, Gennadiy P. Belov. Ethylene and carbon monoxide copolymerization catalyzed by supported palladium catalyst: Journal of Molecular Catalysis A: Chemical 325 (2010) 60~64.

DOI: 10.1016/j.molcata.2010.03.033

Google Scholar

[10] TianEn Zhang, Gbe Love, JunWei Chen etc. Chemistry and bonding, 2005, 27(6): 366~369. In Chinese.

Google Scholar

[11] Axet M R, Amoroso F, Bottari G, D'Amorat A, Zangrando E, Faraone F, Drommi D, Saporita M, Carfagna C, Natanti P, Seraglia R, Milani B. 2009, 28: 4464~4474.

DOI: 10.1021/om900300w

Google Scholar