Facile Synthesis of TiO2 Hollow Spheres with Enhanced Photocatalytic Activity

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TiO2 hollow spheres were synthesized through a facile bubble-template hydrothermal method. Microscopic and diffraction data indicated that the well-crystallized rutile-phase product was composed of self-assembly nanorods with an average diameter of 35 nm. The as-grown product showed high photocatalytic activities in degradation of organic pollutants such as rhodamine B under UV irradiation. It was found that almost all rhodamine B can be decomposed after only 30 minutes of UV irradiation. The enhanced photocatalytic performances were probably attributed to the structure of TiO2 hierarchical hollow spheres, which supplied higher specific surface area and faster electron transport.

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Advanced Materials Research (Volumes 641-642)

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266-269

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January 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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[1] A. Fujishima, K. Honda, Electrochemical photolysis of water at a semiconductor electrode, Nature 238 (1972) 37–38.

DOI: 10.1038/238037a0

Google Scholar

[2] A. Fujishima, T. N. Rao, D. A. Tryk, Titanium dioxide photocatalysis, J. Photochem. Photobiol. C: Photochem Rev. 1 (2000) 1-21.

Google Scholar

[3] B. O'Regan, M. Gratzel, A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films, Nature 353 (1991) 737-740.

DOI: 10.1038/353737a0

Google Scholar

[4] G. Wang, Q. Wang, W. Lu, J. H. Li, Photoelectrochemical study on charge transfer properties of TiO2-B nanowires with an application as humidity sensors, J. Phys. Chem. B 110 (2006) 22029-22034.

DOI: 10.1021/jp064630k

Google Scholar

[5] H. Xu, F. L. Jia, Z. H. Ai, L. Z. Zhang, A general soft interface platform for the growth and assembly of hierarchical rutile TiO2 nanorods spheres, Cryst. Growth & Design, 7 (2007) 1216-1219.

DOI: 10.1021/cg0609419

Google Scholar

[6] Z. Miao, D. S. Xu, J. H. Ouyang, G. L. Guo, X. S. Zhao, Y. Q. Tang, Electrochemically induced Sol-Gel preparation of single-crystalline TiO2 nanowires, Nano Lett. 2 (2002) 717-720.

DOI: 10.1021/nl025541w

Google Scholar

[7] T. Kubo, A. Nakahira, Local structure of TiO2-derived nanotubes prepared by the hydrothermal process, J. Phys. Chem. C 112 (2008) 1658-1662.

DOI: 10.1021/jp076699d

Google Scholar

[8] Y. Kondo, H. Yoshikawa, K. Awaga, M. Murayama, T. Mori, K. Sunada, S. Bandow, S. Iijima, Preparation, photocatalytic activities, and dye-sensitized solar-cell performance of submicron-scale hollow spheres, Langmuir, 24 (2008) 547-550.

DOI: 10.1021/la702157r

Google Scholar

[9] J. G. Yu, W. Liu, H. G. Yu, A one-spot approach to hierarchically nanoporous Titania hollow microspheres with high photocatalytic activity, Cryst. Growth & Design, 8 (2008) 930-934.

DOI: 10.1021/cg700794y

Google Scholar

[10] X. X. Li, Y. J. Xiong, Z. Q. Li, Y. Xie, Large-scale fabrication of TiO2 hierarchical hollow spheres, Inorg. Chem. 45 (2006) 3493-3495.

DOI: 10.1021/ic0602502

Google Scholar

[11] J. Y. Kim, S. B. Choi, D. W. Kim, S. W. Lee, H. S. Jung, J. K. Lee, K. S. Hong, Surfactant-assisted shape evolution of thermally synthesized TiO2 nanocrystals and their applications to efficient photoelectrodes, Langmuir, 24 (2008) 4316-4319.

DOI: 10.1021/la703497e

Google Scholar