Synthesis of PMMA by Single-Electron Transfer Radical Polymerization Using Benzyl Chloride as Initiator

Chang Qing Fu; Xiao Bo Wei; Liang Shen

doi:10.4028/www.scientific.net/AMR.645.85

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HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 645Synthesis of PMMA by Single-Electron Transfer...

Synthesis of PMMA by Single-Electron Transfer Radical Polymerization Using Benzyl Chloride as Initiator

Abstract:

Single electron transfer living radical polymerization (SET-LRP) has developed to be a robust tool for the construction of well-designed polymers. This paper reports the influence of one cheaper initiator on the SET-LRP process. The SET-LRP of methyl methacrylate (MMA) initiated with benzyl chloride and catalyzed by Cu(0)/PMDETA at 25°C in methanol is described. The polymerization kinetics was recorded. The reactions followed first-order kinetic in monomer consumption and the molecular weights increased linearly with conversion while retaining narrow molecular weight distribution. Therefore, it is plausible that SET-LRP of MMA initiated with benzyl chloride process to yield well defined macromolecules.

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Periodical:

Advanced Materials Research (Volume 645)

Pages:

85-88

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.645.85

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Online since:

January 2013

Authors:

Chang Qing Fu, Xiao Bo Wei, Liang Shen

Keywords:

Benzyl Chloride, Methyl Methacrylate, Single Electron Transfer Living Radical Polymerization (SET-LRP)

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