Research on Methane Hydrate Meta-Stable Property of Gas Hydrates for Application to Natural Gas Storage and Transportation

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Gas hydrates are group ice-like crystalline compounds, which form through a combination of water and suitably sized guest molecules under low temperature and high pressure conditions. The important properties of hydrate are very high gas to solid ratio, 1m3 of hydrate may contain up to 175m3 of gas (at standard condition). When the conditions change, the methane hydrate can dissociate to methane and water. Hydrate meta-stable (self-preservation) property has been reported by some researchers in recent years. If we can utilize the property economically in addition to its high-density gas containing property, it is possible to store and transport stranded natural gas at higher temperature and lower pressure compared to the conventional liquid natural gas method. The authors conducted laboratory experiments of methane hydrate dissociation in order to examine its potential for application to natural gas storage and transportation. As the result, relatively extremely slow dissociation was confirmed within temperature range between -7.5°C and -3°C. These results seem to be very promising for practical application of self preservation property to natural gas storage and transportation.

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97-102

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March 2013

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[1] Collett, T.S., 2004. Gas Hydrates as a Future Energy Resource. Sidebars: U.S. projects under way, 2004.

Google Scholar

[2] Chatti, I., Delahaye, A., Fournaison, L., and Petitet, J.P., 2005. Benefits and Drawbacks of Clathrate Hydrates: a Review of Their Areas if Interest. Energy Conversion and Management, 46(2005)1333-1343.

DOI: 10.1016/j.enconman.2004.06.032

Google Scholar

[3] Goel, N., Wiggins, M. and Shah, S., 2001. Analytical Modeling of Gas Recovery from in Situ Hydrates Dissociation. Journal of Petroleum Sciences and Engineering, 29(2001) 115-127.

DOI: 10.1016/s0920-4105(01)00094-8

Google Scholar

[4] Holder, G.D., and Angert, P.F., 1982. Simulation of gas production from a reservoir containing both gas hydrates and free natural gas. Paper SPE 11105 presented at the 1982 Annual Technical Conference and Exhibition, New Orleans, Sept(1982)26–29.

DOI: 10.2118/11105-ms

Google Scholar

[5] Holder, G.D., Angert, P.F., John, V.T., Yen, S., 1982. A thermodynamic evaluation of thermal recovery of gas from hydrates in the earth. J. Pet. Techno, (1982)1127–1132.

DOI: 10.2118/8929-pa

Google Scholar

[6] Ji, C., Ahmadi, G., and Smith, D.H., 2004. Constant rate natural gas production from a well in a hydrate reservoir. Energy Conversion and Management, 44(2004) 2403-2423.

DOI: 10.1016/s0196-8904(03)00010-4

Google Scholar

[7] Gudmundsson, J.S. and Mork, M., "Stranded gas to hydrate for storage and transport", 2001 International Gas Research Conference, Amsterdam (2001), November 5-8.

Google Scholar

[8] Taylor, M., Dawe, R.A., and Thomas, S., "Fire and Ice: Gas Hydrate Transportation – A possibility for the Caribbean Region", SPE 81022, presented at the SPE Latin American and Caribbean Petroleum Engineering Conference held in Port-of-Spain, Trinidad, West Indies (2003), April 27-30.

DOI: 10.2118/81022-ms

Google Scholar

[9] Yakushev, V.S. and Istomin, V.A., "Gas hydrates self-preservation effect", Physics and chemistry of Ice, Hokkaido University Press, Sapporo, Japan (1992), 136-139.

Google Scholar

[10] Stern, L., Circone, S., Lirby, S. and Durham, W., "Anomalous preservation of pure methane hydrate at 1 atm", Journal of Physical Chemistry, 105 (2001), 1756-1762. Gudmundsson, J.S., Parlaktuna, M., and Khokhar, A.A., "Storing natural gas as frozen hydrate", SPE Production and Facility (1994), 69-73.

DOI: 10.1021/jp003061s

Google Scholar

[11] Davidson, D.W., Garg, S.K., Gough, S.R., Handa, Y.P., Ratcliffe, C.I., Ripmeester, J.A., Tse, J.S., and Lawson, W.F., "Laboratory analysis of a naturally occurring gas hydrate from sediment of the Gulf of Mexico", Geochimica et Cosmochimica Acta, 50 (1986), 619-623.

DOI: 10.1016/0016-7037(86)90110-9

Google Scholar

[12] Fitzgerald A. and Taylor M., "Offshore Gas-to-Solid Technology", SPE paper 71805, presented at the Offshore Europe Conference held in Aberdeen, UK (2001), 4-7 September.

Google Scholar

[13] Gudmundsson, J.S. and Borrehaug, A., "Frozen hydrate for transport of natural gas", Proc. 2nd Intl. Conf. Natural Gas Hydrates, Toulouse, France (1996), June 2-6, 415-422.

Google Scholar

[14] Gudmundsson, J.S., Mork, M. and Graff, O.F., "Hydrate non-thpipeline technology", Proc. 4 Intl. Conf. Gas Hydrates, Yokohama (2002), May 19-23, 997-1002.

Google Scholar

[15] Gudmundsson, J.S., Hveding, F., and Borrehaug, A., "Frozen hydrate compared to LNG", Department of Petroleum Engineering and Applied Geophysics, Norwegian Institute of Technology, Trondheim, January (1995).

Google Scholar

[16] Gudmundsson, J.S., Anderson, V., Levik, O.I., and Parlaktuna, M., "Hydrate Concept for Capturing Associated Gas", SPE 50598, the European Petroleum Conference, 20-22 October 1998, The Hague, Netherlands (1998), Conference Proceedings, 247- 258.

DOI: 10.2118/50598-ms

Google Scholar