Preparation of High Heat-Resistant Profile Based on PVC/α-MSAN/ABS Ternary Blends

Abstract:

In this paper, ternary blends of PVC mixed with α-methyl styrene-acrylonitrile (α-MSAN) and toughening modifier was prepared, with the aim to obtain a high performance PVC profile with an improved heat resistant temperature, better impact property and good processability. The results of dynamic mechanical analysis (DMA) showed the good miscibility owing to the additional intermolecular interaction between α-hydrogen of PVC and AN of α-MSAN. The glass transition temperature (Tg) and vicat softening temperature (VST) were improved remarkably with introduction of α-MSAN due to excellent heat resistant property of α-MSAN. With regard to mechanical and process properties, the impact strength and dynamic rheological property were evaluated.

• Periodical: Advanced Materials Research (Volumes 690-693)
• Pages: 1581-1585
• DOI: https://doi.org/10.4028/www.scientific.net/AMR.690-693.1581
• Online since: May 2013
• Authors: Xing Wang, Shao Yun Guo, Fei Hu Yang
• Keywords: ABS, Heat Resistance, Poly(vinyl chloride), Toughness, α-MSAN

References

[1] O.G. Hansen: Medical Device Technology. Vol. 19 (2008), p.17

[2] L. Cappucci: Plast. Addi. Comp. Vol. 11(2009), p.22

[3] J.W. Summers: J. Vinyl. Addit. Techn. Vol 3(1997), p.130

[4] M.W. Pan, L.C. Zhang, J.F. Yuan and X.D. Shi: J. App. Polym. Sci. Vol. 95 (2005), p.419

[5] B. Saethre and M. Gilbert: Polymer. Vol. 37 (1996), p.3379

[6] M.T. Takemori: Polym. Eng. Sci. Vol. 19 (1979), p.1104

[7] L.T. Yang, D.H. Sun, Y.F. Li, G.D. Liu and J.G. Gao: J. App. Polym. Sci. Vol. 88 (2003), p.201

[8] H.S. Moon, W.M. Choi, M.H. Kim and O.O. Park: J. App. Polym. Sci. Vol. 104 (2007), p.95

[9] Q.G. Wang, X.H. Zhang and S.Y. Liu et al.: Polymer. Vol. 46 (2005), p.10614

[10] C.H. Kim, J.K. Park and T.S. Hwang: Polym. Eng. Sci. Vol. 36 (1996), p.535

[11] S. Stoeva, P. Kartalov and K. Jankova: J. Polym. Sci. Part B: Polym. Phys. Vol. 36 (1998), p.1595

[12] J.J. Zhou, L. Su and F. You et al.: J. App. Polym. Sci. Vol. 121 (2011), p.1725

[13] A. Hassan and B. Haworth: J. Mater. Process. Technol. Vol. 172 (2006), p.341