Synthesis of Quaternary Ammonium Cationic Polymer PEA

Rong Ming Zhang; Hong Man Shan; Min Zhao; Dong Hui Ma; Wei Li

doi:10.4028/www.scientific.net/AMR.690-693.1599

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 690-693Synthesis of Quaternary Ammonium Cationic Polymer...

Synthesis of Quaternary Ammonium Cationic Polymer PEA

Abstract:

The cationic polymer PEA was synthesized by ring-opening reaction and quaterisation with epichlorohydrin and β-hydroxy alkyl propyl ether amine as the main materials.Study on the efffect of rate of charge, reaction time and reaction temperature on cationic degree and epoxy value. Capability of adsorption on the sand and anti-swelling resistance were studied. The results showed that the best polymerization conditions as follows,reaction temperature was 60 °C, reaction time was 6 h, the rate of charge of epichlorohydrin toβ-hydroxy alkyl propyletheramine was 2.5:1. Under these conditions , the cationic degree of PEA was 3.962 mmol/g, epoxy value was 0.12. Then it was performed the water absorption.

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Periodical:

Advanced Materials Research (Volumes 690-693)

Pages:

1599-1603

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.690-693.1599

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Online since:

May 2013

Authors:

Rong Ming Zhang, Hong Man Shan, Min Zhao, Dong Hui Ma, Wei Li

Keywords:

Cationic Degree, Epoxy Value, β-Hydroxy Alkyl Proply Ether Amine

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