Emulsifier-Free Core-Shell Hybrid Latexes from Castor Oil-Based Waterborne Polyurethane and Polyacrylate Containing Fluorine and Silicon

Chang Qing Fu; Meng Xu; Zheng Yang; Qing Gui Lv; Liang Shen

doi:10.4028/www.scientific.net/AMR.690-693.1620

Paper Titles

Synthesis of Quaternary Ammonium Cationic Polymer PEA
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Synthesis of UV-Writing Fluorinated Polymer for Organic Optical Waveguide
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The Studies on Crystallization of Polypropylene (PP)/Nano-TiO₂ Composites under Microwave Irradiation
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The Swelling Kinetics Study of Hydrogels Prepared by the Different Finesses Degrees of Eupatorium Adenophorum
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Emulsifier-Free Core-Shell Hybrid Latexes from Castor Oil-Based Waterborne Polyurethane and Polyacrylate Containing Fluorine and Silicon
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Research on the Relationship between the Productivity of Antarctic Krill Chitin and its Fineness of Grind
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Synthesis and Properties of a Castor Oil-Based UV-Oligomer Comprising of Side-Chain Benzophenone
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The Best Dosage of Polymer Dispersant in WDG by Zata Potential Method
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The Surface Modification and Characteristics of Useful Expanded PTFE Composites by Photo-Radiation Methods
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Emulsifier-Free Core-Shell Hybrid Latexes from Castor Oil-Based Waterborne Polyurethane and Polyacrylate Containing Fluorine and Silicon

Abstract:

The core-shell polyurethane-acrylate(PUA) emulsion containing fluorine and silicon in the core was synthesized by “one-pot” emulsion polymerization in the presence of castor oil-based polyurethane without traditional emulsifier, using methyl methacrylate (MMA), butyl acrylate (BA) as the main monomers, dodecafluoroheptyl methacrylate (G04), γ-methacryloxy propyl trimethoxyl silane (KH-570) as the functional monomers. The structure and properties of the fluorinated-silicated PUA and their films were characterized by transmission electron microscopy (TEM), Fourier transform infrared spectrum (FT-IR) and contact angle testing. The results showed that fluorine and silicon monomers had effectively copolymerized with acrylic monomers and a core-shell structure in the latex was formed. The water contact angle for film-air interface is 92.5^o, and the cetane contact angle for film-air interface is 47.5^o.