Elemental Analysis and Wettability Properties of Polyene with Epoxidised Oil Based Coating

Article Preview

Abstract:

Presence of chlorine in by product of degradation process from polyvinyl chloride was analysed through structural feature changes and elemental analysis. Coating samples with polyene was also tested for its wettability via contact angle. Analyzing the elimination of chlorine content from polyvinylchloride through chemical dechlorination with tetrahydrofuran (THF) has been studied via FTIR spectra, energy-dispersive x-ray spectroscopy (EDS) and static contact angle measurement. Qualitative value of decreasing chlorine content of polyene at 2 hours reaction time was found to be about 96% from supplied PVC. All treated samples at different reaction time of polyene synthesize showed good wettability properties since the contact angle value were less than 90o.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

389-393

Citation:

Online since:

May 2013

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] Huggett, C. and B.C. Levin, Toxicity of the pyrolysis and combustion products of poly(vinyl chlorides): A literature assessment. Fire and Materials, (1987). 11(3): pp.131-142.

DOI: 10.1002/fam.810110303

Google Scholar

[2] López, A., et al., Dechlorination of fuels in pyrolysis of PVC containing plastic wastes. Fuel Processing Technology, (2011). 92(2): pp.253-260.

DOI: 10.1016/j.fuproc.2010.05.008

Google Scholar

[3] Balci, S., O. Birer, and S. Suzer, Photosensitization of PVC dehydrochlorination by hydroquinone for improved optical and electrical properties. Polymer, (2004). 45(21): pp.7123-7128.

DOI: 10.1016/j.polymer.2004.08.037

Google Scholar

[4] Guo, L., Poly(ethylene glycol)s catalyzed homogeneous dehydrochlorination of poly(vinyl chloride) with potassium hydroxide. Polymer, (2001). 42(13): pp.5581-5587.

DOI: 10.1016/s0032-3861(01)00037-4

Google Scholar

[5] Rahmah, M., et al., Degradation Behaviour and Kinetics of UV Cured Epoxidised Soybean Oil Derivatives. Advanced Materials Research, (2011). 230-232: pp.94-98.

DOI: 10.4028/www.scientific.net/amr.230-232.94

Google Scholar

[6] Abdrahman, M.F. and E.S. Zainudin, Properties of Kenaf Filled Unplasticized Polyvinyl Chloride Composites. Key Engineering Materials, (2011). 471-472: pp.507-512.

DOI: 10.4028/www.scientific.net/kem.471-472.507

Google Scholar

[7] Sobczak, N., et al., Factors affecting wettability and bond strength of solder joint couples. Pure and Applied Chemistry, (2007). 79(10): pp.1755-1769.

DOI: 10.1351/pac200779101755

Google Scholar

[8] Shafrin, E.G. and W.A. Zisman, Constitutive Relations in the Wetting of Low Energy Surfaces and the Theory of the Retraction Method of Preparing Monolayers. Journal of Physical Chemistry, (1960). 64(5): pp.519-524.

DOI: 10.1021/j100834a002

Google Scholar