The Effect of Boric Acid Addition on the Performance of a Gelled Electrolyte

Article Preview

Abstract:

The aim of this study is to evaluate the effect of boric acid as an additive for gelled electrolytes. Cyclic voltammetry (CV), linear sweep voltammetry (LSV), electrochemical impedance spectroscopy (EIS) and an equivalent circuit analysis were employed to study the electrochemical performance of the gelled electrolyte with the addition of varying amounts of boric acid. Scanning electron microscope (SEM) was employed to observe the grid corrosion in corrosion test. For moderate contents of boric acid, the electrode capacity improved, as well as the oxygen evolution profermance. However, the adverse effects of boric acid were found to include increased electrical resistance, decreased hydrogen evolution overpotential and promote the corrosion of the grid. The experimental results indicates that the optimum content was 0.4wt.%.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 712-715)

Pages:

321-324

Citation:

Online since:

June 2013

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] Y. Chang, X. X. Mao and H.Y. Chen: J. Power Source V. 191 (2009), P. 176

Google Scholar

[2] W. A. Badawy and S. S. El-Egamy: J. Power Source V. 55 (1995), P. 11

Google Scholar

[3] K.Saminathan and N.Jayaprakash: J.Power Sources V. 160 (2006), P.1410

Google Scholar

[4] A. Bhattacharya and I. N. Basumallick: J. Power Source V.113 (2003), P. 382

Google Scholar