Thermodynamic Behavior of SiH2Cl2 in Polysilicon Production by Siemens Process

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Abstract:

The present of SiH2Cl2 (DCS) is a big problem because of its instability. The content of SiH2Cl2 should be controlled below somewhat concentration. Therefore, the present study is aimed at investigating the thermodynamic behavior of SiH2Cl2 in polysilicon production by Siemens process in order to provide effective theory for the production process. The effect of pressure (1-5atm), feeding ratio of H2 to SiHCl3 (2-50) and temperature (1000-1500K) have been studied in the paper. The results show that the productivity ratio of DCS increases with increasing pressure and increases firstly and then decreases with increasing feeding ratio or temperature. In a word, the pressure have biggest effect on productivity ratio of DCS compared to temperature and feeding ratio.

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Periodical:

Advanced Materials Research (Volumes 712-715)

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325-328

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June 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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