Preparation and Characterization of Terpene-Based Diol from Terpene-Maleic Anhydride Using Lithium Aluminum Hydride as Reductant

Xiao Dong Tang; Jian Ling Xia; Shou Hai Li; Kun Huang; Mei Li; Zhi Qu Lu

doi:10.4028/www.scientific.net/AMR.721.266

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HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 721Preparation and Characterization of Terpene-Based...

Preparation and Characterization of Terpene-Based Diol from Terpene-Maleic Anhydride Using Lithium Aluminum Hydride as Reductant

Abstract:

A Diol with endocyclic structure that is 1-methyl-4-isopropyl-bicyclo [2,2,-2,3-two hydroxymethyl-5-Octene (MIBHO), deriving from terpene, was synthesized using the aid of lithium aluminium hydride (LAH) as reductant in THF media at 65 °C. The optimum synthesis conditions were confirmed by analysing the factors on reacting temperature, reacting time, different solvents and reductants. The molecular structure of the novel compound has been characterized by FT-IRGC-MS and ¹H-NMR analysis. The data reveal that LAH could effectively reduce terpene maleic anhydride to corresponding alcohol, and the conversion rate of raw material could reach 84%.

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Periodical:

Advanced Materials Research (Volume 721)

Pages:

266-269

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.721.266

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Online since:

July 2013

Authors:

Xiao Dong Tang, Jian Ling Xia, Shou Hai Li, Kun Huang, Mei Li, Zhi Qu Lu

Keywords:

Lithium Aluminium Hydride, Reduction, Terpene Maleic Anhydride

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References

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