Remediation of Hexavalent Chromium Polluted Ground Water by PRB

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Abstract:

The zero-valent iron (Fe0) and the activated carbon were used as reaction mediums, the reactivity characteristics and removal effect of hexavalent chromium (Cr (VI)) contaminated ground water using Fe0/AC-PRB were investigated. The results showed that AC adsorbed Cr (VI) under the pH conditions of influent, and Cr (VI) was removed. Also, the chromium could be deoxidized by zero-valent iron effectively, when simulated groundwater containing 10mg/L hexavalent chromium was continuously input. During the process, the redox products, Fe3+ and Cr3+, precipitated on the reaction media without transferring into downstream water. The pH value increased from 7.0 in influent to 8.0 in effluent, and the total iron concentration of effluent was below 0.30mg/L. Chromium was distributed mainly in the form of organic/sulphide fraction and residue fraction when the aquifer was flushed with deionized water, Moreover, bioavailable weak acid extractable fraction was not detected, indicatinga low ecological risk of chromium remained in the aquifer.

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Advanced Materials Research (Volumes 726-731)

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1724-1731

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August 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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[1] Aisen Cong, Ground water pollution control by underground continuous wall, Geology and Prospecting. 33(1997) 59-64.(in Chinese)

Google Scholar

[2] Hua Hao, City groundwater pollution status and countermeasure research in China, Water Resources Development Research. 3(2004) 23-25. (in Chinese)

Google Scholar

[3] Weiying Rong, Qixing Zhou, Soil pollution processes,their affecting factors,and phytoremediation of chromium slag heads: A review, Chinese Journal of Ecology. 29(2010) 598-604. (in Chinese)

Google Scholar

[4] Lijun Wang, Shen Zhang, Cr(Ⅲ) and Cr(Ⅵ) morphological transformation in Soil water, Environmental Science. 3(1982) 38-42. (in Chinese)

Google Scholar

[5] Tongzhou Liu, D. C. W. Tsang, I. M. C. Lo, Chromium(VI) Reduction Kinetics by Zero-Valent Iron in Moderately Hard Water with Humic Acid: Iron Dissolution and Humic Acid sorption, Environ. Sci. Technol. 42(2008) 2092-2098.

DOI: 10.1021/es072059c

Google Scholar

[6] M. R. Boni, S. Sbaffoni, The potential of compost-based biobarriers for Cr(VI) removal from contaminated groundwater: Column test, Journal of Hazardous Materials. 166(2009) 1087-1095.

DOI: 10.1016/j.jhazmat.2008.12.036

Google Scholar

[7] Hui Xu, Yanqing Wu, Experiment on sexavalent chromium transport in seepage sand box with permeable reactive barrier, Ecology and Environmental Sciences. 19(2010) 1941-1946. (in Chinese)

Google Scholar

[8] Jia Wu, Xiujun Tian, Jin Wang, Treatment of Cr(Ⅵ) in Deoxygenated Simulated Groundwater Using Nanoscale Zero-Valent Iron, Environmental Science. 31(2010) 645-652. (in Chinese)

Google Scholar

[9] Li Li, Yeyao Wang, Fansheng Meng, Influence of media proportioning upon remedial efficiency of PRB, Environmental Engineering. 26(2008) 91-93. (in Chinese)

Google Scholar

[10] R. Thiruvenkatachari, S. Vigneswaran, R. Naidu, Permeable reactive barrier for groundwater remediation, Journal of Industrial and Engineering Chemistry. 14(2008) 145-156.

DOI: 10.1016/j.jiec.2007.10.001

Google Scholar

[11] M. S. H. Mak, I. M. C. Lo, Environmental life cycle assessment of permeable reactive barriers: effects of construction methods, reactive materials and groundwater constituents, Environmental Science & Technology. 45(2011) 10148-10154.

DOI: 10.1021/es202016d

Google Scholar

[12] A. B. Cundy, L. Hopkinson, R. L. D. Whitby, Use of iron-based technologies in contaminated land and groundwater remediation: A review, Science of The Total Environment. 400(2008) 42-51.

DOI: 10.1016/j.scitotenv.2008.07.002

Google Scholar

[13] J. Pempkowiak, A. Sikora, E. Biernacka, Speciation of heavymetals in marine sediments vs their bioaccumulation by mussels, Chemosphere. 39(1999) 313-32.

DOI: 10.1016/s0045-6535(99)00112-5

Google Scholar

[14] J. Mendoza, T. Garrido, G. Castillo, Metal availability and uptake by sorghum plants grown in soils amended with sludge from different treatments, Chemosphere. 65(2006) 2304-2312.

DOI: 10.1016/j.chemosphere.2006.05.012

Google Scholar

[15] Jun Yang, Yunxiu Wang, Yinsheng Zhang, Mechanism of treatment of chromium—containing wastewater by activated carbon, Journal of Polytechnic University. 19(1989) 13-22. (in Chinese)

Google Scholar

[16] United States Environmental Protection Agency, An in-situ permeable reactive barrier for the treatment for hexavalent chromium and trichloroethylene in ground water: Volume 1 Design and Installation. Washington DC: 1999, EPA/600/R-99/095a.

Google Scholar

[17] United States Environmental Protection Agency, An in-situ permeable reactive barrier for the treatment for hexavalent chromium and trichloroethylene in ground water: Volume 2 Performance Monitoring. Washington DC: 1999, EPA/600/R-99/095b.

Google Scholar

[18] Y. P. Wang, L. J. Wang, P. Y. Peng, Treatment of naphthalene derivatives with iron-carbon micro-electrolysis, Transactions of Nonferrous Metals Society of China. 16(2006) 1442-1447.

DOI: 10.1016/s1003-6326(07)60035-1

Google Scholar

[19] L. Fan, J. R. Ni, Y. J. Wu, Treatment of bromoamine acid wastewater using combined process of micro-electrolysis and biological aerobic filter, Journal of Hazardous Materials. 162(2009) 1204-1210.

DOI: 10.1016/j.jhazmat.2008.06.006

Google Scholar

[20] R. T. Wilkin, R. W. Puls, G. W. Sewell, Long-Term Performance of Permeable Reactive Barriers Using Zero-Valent Iron: Geochemical and Microbiological Effects, Ground Water. 41(2003) 493-503.

DOI: 10.1111/j.1745-6584.2003.tb02383.x

Google Scholar

[21] K. J. Cantrell, D. I. Kaplan, T. W. Wietsma, Zero-valent iron for the in situ remediation of selected metals in groundwater, Journal of Hazardous Materials. 42(1995) 201-212.

DOI: 10.1016/0304-3894(95)00016-n

Google Scholar