Study on Adsorption and Remove of Fluorine from Water by Modified Zeolite

Article Preview

Abstract:

A modified Zeolite to be prepared and its performance of removing fluorine from containing fluoride water was reported. Firstly, using zeolite 4A as skeleton, by means of carrying to adsorb Fe3from containing ferri ions solution, which the zeolite can be modified and the coordination metal center are formed. Based on mechanism of ligand exchange, a new material of removing deeply fluorine from water was got. Secondly , the results show that this modified zeolite has favourable adsorbing capacity for fluorine from water, when fluorine concentration is about 4~25 mg.L-1, above 99.0% of fluorine can be removed from water. The static saturation adsorbing capacity is 20.1 mg.g-1, by following conditions:the pH of water range of 5-8; solid-to-liquid ratio of 1:50 and room temperature.Common-ions in water do not make affect to adsorbing fluorine by the zeolite and high selection in process of removing fluorine has been demonstrated.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 726-731)

Pages:

2295-2299

Citation:

Online since:

August 2013

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Apambire W.B., Boyle O.R., Michel F.A., Geo-chemistry, genesis, and health implications of fluoriferous groundwaters in the upper regions of ghana, Environmetal Geoiogy, 1997,33(1):13

DOI: 10.1007/s002540050221

Google Scholar

[2] E.J. Reardon, Y. Wang, A Limestone Reactor for fluoride removal from wastewaters, Environ. Sci. Technol. 34 (2000) 3247–3253

DOI: 10.1021/es990542k

Google Scholar

[3] M. Amini, K. Mueller, K.C. Abbaspour, T. Rosenberg, M. Afyuni, K.N. Møller, M. Sarr, C.A. Johnson, Statistical modeling of global geogenic fluoride contamination in groundwaters, Environ. Sci. Technol. 42 (2008) 3662–3668.

DOI: 10.1021/es071958y

Google Scholar

[4] N.J. Chinoy, Effects of fluoride on physiology of animals and human beings[J], Indian J. Environ. Toxicol. 1 (1991) 17–32

Google Scholar

[5] P.T.C. Harrison, Fluoride in water: a UK perspective[J]. J.Fluorine Chem. 126 (2005) 1448–1456

Google Scholar

[6] M. Amini, K. Mueller, K.C. Abbaspour, T. Rosenberg, M.Afyuni, K.N. Møller, M. Sarr, C.A. Johnson, Statistical modeling of global geogenic fluoride contamination in groundwaters[J], Environ. Sci. Technol. 42 (2008) 3662–3668.

DOI: 10.1021/es071958y

Google Scholar

[7] Ministry of health of the People's Republic of China and the Standardization Administration of China. GB5749-2006. The Monitoring Method of Drinking Water Standards[Z].

Google Scholar

[8] M.G. Sujana, R.S. Thakur, S.B. Rao, Removal of fluoride from aqueous solution by using alum sludge,J. Colloid Interface Sci. 206 (1998) 94–101

DOI: 10.1006/jcis.1998.5611

Google Scholar

[9] F. Shen, X. Chen, P. Gao, G. Chen, Electrochemical removal of fluoride ions from industrial wastewater, Chem. Eng. Sci. 58 (2003) 987–993

DOI: 10.1016/s0009-2509(02)00639-5

Google Scholar

[10] S.P. Kamble, G. Deshpande, P.P. Barve, S. Rayalu, Adsorption of fluoride from aqueous solution byalumina of alkoxide nature: Batch and continuous operation, Desalination264 (2010) 15–23

DOI: 10.1016/j.desal.2010.07.001

Google Scholar

[11] P. Sehn, Fluoride removal with extra low energy reverse osmosis membranes: three years of large scale field experience in Finland, Desalination 223 (2008) 73–84

DOI: 10.1016/j.desal.2007.02.077

Google Scholar