Effects of Additives on the Reductive Decomposition of Phosphogypsum in the CO Atmosphere

Article Preview

Abstract:

The effect of the reaction time and the amount of additives on the decomposition rate and temperature of phosphogypsum were studied in the weak reducing atmosphere of 3%Vol CO by using the mixture of phosphogyp-sum and a certain percentage of CaCl2, Fe2O3 and MgO additives. The result shows that the decomposition rate of phosphogypsum reached 85% by adding CaCl2 and Fe2O3, and the decomposition temperature of phosphogypsum was only 950°C which was 100 °C lower than the one of decomposition reaction of phosphogypsum without any adductives. And the addition of MgO had no significant effects on the decomposition of phosphogypsum under the same condition.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 726-731)

Pages:

331-339

Citation:

Online since:

August 2013

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] Feng Jinhuang. Comprehensive use of phosphogypsum (in Chinese)[J]. Inorganic chemicals industry, 2001,33(004):34-36.

Google Scholar

[2] Zheng Suyun,Chen Tong, Zheng Linshu. Comprehensive Utilization Actuality and Research Progress of Phosphogypsum(in Chinese).Chemical Production and Technology2003,10(4):33-35.

Google Scholar

[3] Guo Cuixiang, Shi Lei, Niu Dongjie, et al. Discussion on Comprehensive Utilization of Phosphogypsum (in Chinese) [J]. China Reaources Comprehensive Utilization, 2006, 24(2): 29-32.

Google Scholar

[4] Wang Xinlong, Zhang Zhiye, Yang X iushan , et al. Analysis on new approaches for utilization of phosphogypsum in China(in Chinese) [J]. ModernChemical Industry, 2011, 31(5):1-5.

Google Scholar

[5] Yang Min. Impurities in Phosphogypsum and Its Utilization(in Chinese). Yunnan Chemical Technology,2010,37(2):37-39.

Google Scholar

[6] Yang Bulei. Comprehensive Utilization of Phosphogypsum(in Chinese). Guizhou Chemical Industry,2010,35(1):28-30.

Google Scholar

[7] Wang Chengbo, Zhang Zhiye, Chen Xin. Experiment studyon the production of sulfuric acid integrated with cement by new reducing agent from phosphogypsum raw materia(in Chinese). Phosphate & Compound Fertilizer, 2007, 22(1):21-23.

Google Scholar

[8] Gruncharov I, Kashchieva E, Dombalov I, et al. The influence of gudron additive on the structure of the solid phase from the thermal decomposition of phosphogypsum. Thermochimica Acta.1988,133:233-240

DOI: 10.1016/0040-6031(88)87163-6

Google Scholar

[9] Fang Zuguo, Ning Ping, Yang Yuehong, et al. Influence factors of deoxidizing phosphogypsum by compound reducing agent(in Chinese). Chemical Industry and Engineering Progress. 2009, 28(3): 522-527.

Google Scholar

[10] Liu Shaowen, Zhang Xi, Wu Yuanxin, et al. Effect of reacting atmosphere and additives on reaction process for production of sulfuric acid from phosphogypsum(in Chinese). Phosphate & Compound Fertilizer.2008;23.

Google Scholar

[11] Xiao Haiping,Zhou Junhu,Cao Xinyu, et al.Experiments and model of the decomposition of CaSO4 under CO atmosphere(in Chinese).Journal of Fuel Chemistry and Technology. 2005,33(2): 150-154.

Google Scholar

[12] Wang Xuanxuan,Ran Xionglan,Liu Shaowen, et al. Experimental studyontheanalytical method for calcium sulfate in phosphogysum(in Chinese). J. WuhanInst. Tech.. 2010, 32(5): 42-44.

Google Scholar

[13] X. Xiong, Kuangye. Eng. 22 (2002) 93-95.

Google Scholar

[14] K. Zheng, S. B. Yang, C. Rűssel, J.C. Liu, L. Wen, Non-Cryst. Solids. 358 (2012) 387-391.

Google Scholar