Paper Titles

Intercalation of Gelatin in Monohydrate Zirconium Hydrogen Phosphate
p.2113

Numerical Simulation of Thermal Sensitivity for Explosives
p.2116

Synthesis of Dimethyl Carbonate from Carbon Dioxide, Propylene Epoxide and Methanol
p.2120

The Effect of Thickness on the Properties of TGZO Thin Films for Optoelectronic Devices
p.2124

One Step Synthesis of ε-Caprolactam from Cyclohexanone and Hydroxylamine Catalyzed by SO3H-Functioned Ionic Liquids
p.2128

Study on the Elemental Analysis and Relative Molecular Weight of 5U Rock Asphalt
p.2132

Synthesis and Properties of Dispersive Type High Temperature Filtrate Reducer Used in Oil Well Cement
p.2136

Preliminary Study of Preparation and Properties of Activated K-Feldspar-Filled Hydrogel Materials
p.2141

Preparation and Characterization of KGM/PVA Composite Nanofibrous Membranes
p.2145

HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 734-737One Step Synthesis of ε-Caprolactam from...

One Step Synthesis of ε-Caprolactam from Cyclohexanone and Hydroxylamine Catalyzed by SO3H-Functioned Ionic Liquids

Article Preview

Abstract:

One step synthesis of ε-caprolactam from cyclohexanone and hydroxylamine used acidic ionic liquids [HSO3-b-N(CH3)HSO4 as reaction medium and catalyst were investigated. Reaction conditions were investigated to obtain the optimum conditions. The results indicate that the yield of CPO is 35.9% and the yield of CPL is 20.4% under optimal reaction conditions.

You might also be interested in these eBooks

Resources and Sustainable Development

Info:

Periodical:

Advanced Materials Research (Volumes 734-737)

Pages:

2128-2131

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.734-737.2128

Citation:

Cite this paper

Online since:

August 2013

Authors:

He Fang Wang, Hong Tao Liu, Li Yuan Jia, Yuan Yuan Wang, Yan Ji Wang

Keywords:

Cyclohexanone, Hydroxylamine, One Step Synthesis, SO3H-Functioned Ionic Liquids, ε-Caprolactam

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] Liquan Cheng: Fine chemical intermediates. (In Chinese). Vol. 35 (2005), pp.17-23.

[2] Xueping Yang: Chemical Techno-Economics. (In Chinese). Vol. 23 (2005), pp.1-5.

[3] Lixin Yang, Yunfang Wei: Chemical Industry Engineering Progress.(In Chinese). Vol. 234 (2005), pp.96-99.

[4] Pengjia Jian , Youquan Deng: Tetrahedron Letters. Vol. 42 (2001), pp.403-405.

[5] Jiangkun Zhao, Hefang Wang: Journal of Chemical Engineering of Chinese Universities. (In Chinese). Vol.25(2011), p, 838-843.

[6] Ruxiong Li: Reseach and Application on Green Solvent-the Ionic Liquid. Beijing: Chemical Industry Press(2004). (In Chinese).

[7] Christian P M, Raymond A C, Nicholas C D,et al. J Am Chem Soc. Vol.124 (2002) ,P,12932-12933

[8] R.X. Ren, L.D. Zueva, Ou Wei: Tetrahedron Lett, Vol.42(2001), p, 8441~8443.

[9] Andris Zicmanis, Sarmite Katkevica, Peteris Mekss: Catalysis Communications Vol.10 (2009), p, 614–619.

DOI: 10.1016/j.catcom.2008.11.008

[10] Wei Zhang, Wei Wu, Shuzhong Zhang: The Chinese Journal of Process Engineer- ing. (In Chinese). Vol.4.(2004),p, 261-264.

[11] Wei Zhang, Wei Wu, Shuzhong Zhang: Petrol Eum Processing And Petrochemi- cals. (In Chinese). Vol.35(2004), p, 47-50.

[12] Miguel Vilas, Emilia Tojo. A mild and efﬁcient way to prepareε-caprolactam by using a novel salt related with ionic liquids. Tetrahedron Letters. Vol.51 (2010), p, 4125–4128.

DOI: 10.1016/j.tetlet.2010.05.145

[13] Guo Shu,Du Zhengyin,Zhang Shiguo,et al: Green Chem. Vol.8 (2006), p, 296-300.

[14] Qiang Guo, Xianghai Meng: Journal of Northeast Petroleum University. (In Chinese). Vol.36 (2012), p, 64-67.

[15] H. Egberink, C. Van Heerden:Analytica Chimica Acta. Vol. 118 (1980), Issue 2,p, 359–368.

DOI: 10.1016/s0003-2670(01)93612-8

[16] Dishun Zhao: Phase transfer catalysis: principles and applications. Chemical Industry Press (2007). (In Chinese). p, 35–35.