Structure Studies on Order Assemblage of Nickel II Complexes

Yu Liu; Xuan Yang; Hong Kuan Li; Hong Xiao Tian; Jian Gao

doi:10.4028/www.scientific.net/AMR.734-737.2373

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 734-737Structure Studies on Order Assemblage of Nickel II...

Structure Studies on Order Assemblage of Nickel^II Complexes

Abstract:

The nickel^II complex [Ni (C₉H₉O₃)₂(H₂O)₂], Diaqua-bis (ethylvanillinato-O,O')-nickel^II, the Ni^IIatom is located on a twofold axis and is coordinated by two ethylvanillinate anions and two water molecule in a distorted octahedral geometry . The ethylvanillinate ligand chelates to the Ni^II atom through its ethyl and hydroxy O atoms,with greatly differing Ni-O bond distances (2.282(2) Å and 1.9792(16)Å). Adjacent complex link to each other via hydrogen bonds forming the three-dimensional supramolecular structure.

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Periodical:

Advanced Materials Research (Volumes 734-737)

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2373-2376

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.734-737.2373

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Online since:

August 2013

Authors:

Yu Liu, Xuan Yang, Hong Kuan Li, Hong Xiao Tian, Jian Gao

Keywords:

Electrostatic Interaction, Nickel^II Complex, Photosystem Ii, Supramolecular Structure

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