Synthesis and Crystal Structure of a Novel 3D Sm(III) Coordination Polymer with Mixed Ligands

Shu Ju Wang; Yan Wen Tian; Li Xin You; Ya Guang Sun

doi:10.4028/www.scientific.net/AMR.750-752.1765

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 750-752Synthesis and Crystal Structure of a Novel 3D...

Synthesis and Crystal Structure of a Novel 3D Sm(III) Coordination Polymer with Mixed Ligands

Abstract:

The coordination polymer, [Sm₂(HPyImDC)₂Ox (H₂O)₂·6H₂_n [H₃PyImDC = 2-(pyridine-3-yl)-1H-4,5-imidazoledicarboxylic acid, Ox = oxalate], has been synthesized under hydrothermal conditions and characterized by elemental analysis, FT-IR and single crystal X-ray diffraction. It crystallizes in monoclinic, space group C2/c with a = 28.166(6), b = 6.9970(14), c = 16.655(3) Å, V = 2685.4(9) Å³, Z = 4, D_c = 2.298 g/cm³, μ(MoKα) = 4.428 mm^-1, F(000) = 1852, the final R = 0.0412 and wR = 0.1010. The complex forms a three-dimensional (3D) framework structure.

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Periodical:

Advanced Materials Research (Volumes 750-752)

Pages:

1765-1768

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.750-752.1765

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Online since:

August 2013

Authors:

Shu Ju Wang*, Yan Wen Tian, Li Xin You, Ya Guang Sun

Keywords:

2-(pyridine-3-yl)-1H-4,5-imidazoledicarboxylic Acid, Coordination Polymer, Crystal Structure, Oxalate

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