Irreversible Thermodynamic Discussions about Ferroelectric Phase Transitions

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Abstract:

The irreversibility of ferroelectric phase transitions has been studied by using the irreversible thermodynamics. The thermal hysteresis of first-order ferroelectric phase transitions and the polydomain structure of ferroelectrics can be explained on the basis of the principle of minimum entropy production. A conclusion has been derived that the thermal hysteresis is not an intrinsic property of a system in which a first-order ferroelectric phase transition occurs. The finiteness of the systems surface is connected with the thermal hysteresis.

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Advanced Materials Research (Volumes 756-759)

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4419-4422

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September 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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