Corrosion Inhibition of Dissymmetric Bis-Quaternary Ammonium with Imidazoline Ring on Q235 Steel in 1.0 mol•L^-1 Hydrochloric Acid Solution

Abstract:

Dissymmetric bis-quaternary ammonium with imidazoline ring was evaluated for corrosion inhibition efficiency against Q235 steel in 1.0mol•L-1hydrochloric acid solution at room temperature (298K) by gravimetric method, potentiodynamic polarization, electrochemical impedance spect- rum(EIS) and quantum chemical calculation. The results of mass loss and polarization data showed the compound acted as a very good mix-up inhibitor for Q235 steel in 1.0mol•L-1hydrochloric acid solution. EIS results showed that the associated values of the charge transfer resistance (Rct) increase by increasing the additive concentrations and immersing time whereas the associated values of double layer capacitance (Cdl) decrease. These changes in the impedance parameters (Rct and Cdl) are indicative of adsorption of the compound on Q235 steel surface leading to the formation of a protective film. The obtained correlations and Quantum chemical calculations conclusions agree well with the experimental results.

• Periodical: Advanced Materials Research (Volumes 79-82)
• Pages: 1063-1066
• DOI: https://doi.org/10.4028/www.scientific.net/AMR.79-82.1063
• Online since: August 2009
• Authors: Bin Jiang, Min Du, Jing Zhang, Zhao Dong Sun
• Keywords: Acid Media, Corrosion Inhibitor, Dissymmetric Bis-Quaternary Ammonium, Quantum Chemistry Calculation

References

[1] F. Bentiss, M. Lebrini, M. Lagrenee: Corros. Sci. Forum Vol. 747 (2005), p.2915.

[2] Sen. Zhu, Fa, Cheng, Jun Wang, Jiu-guo Yu: Colloids and Surfaces A. Forum Vol. 281(2006), p.35.

[3] F.G. Liu,M. Du,J. Zhang,M. Qiu: Corrosion sci. Forum Vol. 51(2009), p.102.

[4] H. Ashassi-Sorkhabi, B. Shaabani, D. Seifzadeh: Appl. Surf. Sci. Vol. 239 (2005) , p.154.

[5] Y. Yan R.Q. Liu X.Q. Wang, L:J. Chinese sci. for corrosion and protection. Vol. 28(2008).