Preparation of F-Zn-Codoped TiO2 Nanoparticles and its Applications in Photodegradation of Methylene Blue

Article Preview

Abstract:

Nano-F/Zn/TiO2 particles were prepared by sol-gel method using NH4F and Zn(NO3)2 as dopants. The photocatalytic degradation of methylene blue in aqueous solution as simulated wastewater was used to evaluate their photocatalytic activities. The powders were characterized by energy dispersion X-ray spectrum (EDS), X-ray diffraction (XRD) transmission electron microscopy (TEM) and Brunauer-Emmett-Teller (BET) surface area analysis. The results showed that F and Zn elements were doped into TiO2. The appropriate codoping amount for F and Zn were n(F)/n(TiO2)=2% and n(Zn)/n(TiO2)=3% respectively. The degradation rate of methylene blue at 1 h was improved from 73.2% to 86.2% by using F/Zn/TiO2 as photocatalyst.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 79-82)

Pages:

329-332

Citation:

Online since:

August 2009

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2009 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] Z. Wang, C. Chen, F. Wu, B. Zou, M. Zhao, J. Wang and C. Feng: Journal of Hazardous Materials Vol. 164 (2009), p.615.

Google Scholar

[2] E. A. Reyes-Garcia, Y. Sun and K. Reyes-Gil: Journal of Physical Chemistry C Vol. 111 (2007), p.2738.

Google Scholar

[3] F. Pinzari, P. Patrono and U. Costantino: Catalysis Communications Vol. 9 (2006), p.696.

Google Scholar

[4] M. Bowker, D. James, P. Stone, R. Bennett, N. Perkins, L. Millard, J. Greaves and A. Dickinson: Journal of Catalysis Vol. 217 (2003), p.427.

DOI: 10.1016/s0021-9517(03)00074-5

Google Scholar

[5] X. S. Luo, C. J. Zhao and B. Luther-Davies: Optical Materials Vol. 27 (2005), p.1461.

Google Scholar

[6] J. H. Pan and W. I. Lee: Chemistry of Materials Vol. 18 (2006), p.847.

Google Scholar

[7] S. Song, J. Tu, L. Xu, X. Xu, Z. He, J. Qiu, J. Ni and J. Chen: Chemosphere Vol. 73 (2008), p.1401.

Google Scholar

[8] C. Liu, X. Tang, C. Mo and Z. Qiang: Journal of Solid State Chemistry Vol. 181 (2008), p.913.

Google Scholar

[9] B. Xin, Z. Ren, P. Wang, J. Liu, L. Jing and H. FU: Applied Surface Science Vol. 253 (2007), p.4390.

Google Scholar