Rietveld Refinement of the BaTiO3 from X-Ray Powder Diffraction

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Abstract:

The ferroelectric ceramic BaTiO3 was synthesized at 1000 °C for 5 h. The structure of the system under study was refined on the basis of X-ray powder diffraction data using the Rietveld method. The system crystallizes in the space group P4mm(99). The refinement of instrumental and structural parameters led to reliable values for the Rp, Rwp and Rexp.We use the TOPAS software of Bruker AXS to refine this ceramic powders and show its conformation

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Advanced Materials Research (Volumes 79-82)

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593-596

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August 2009

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© 2009 Trans Tech Publications Ltd. All Rights Reserved

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[1] J.F. Meng. R.S. Katiyar &G.T. Zou. Grain size effect on ferroelectric phase transition in Pb1-xBaxTiO3 ceramics.J. Phys. Chem. Solid. 1998, 59(6-7): 1161~1167.

DOI: 10.1016/s0022-3697(97)00139-x

Google Scholar

[2] P.P. Phule S.H. Risbud. Review-Low-temperature synthesis and processing of electronic materials in the BaO-TiO2 system [J]. Journal of Materials Seience, 1990, 25(2B): 1169-1183.

DOI: 10.1007/bf00585422

Google Scholar

[3] M. Oledzka N.E. Brese R.E. Riman. Hydrothermal Synthesis of BaTiO3 on a Titanium-Loaded Polymer Support [J]. Chem. Mater., 1999, 11(7): 1931-(1935).

DOI: 10.1021/cm990169f

Google Scholar

[4] R.N. Viswanath,S. Ramasamy. Preparation and ferroelectric phase transition studies of nanocrystalline BaTiO3[J]. Nanostruct. Mater., 1997, 8(2): 155-162.

DOI: 10.1016/s0965-9773(97)00004-4

Google Scholar

[5] H. Shimooka,M. Kuwabara. Crystallinity and stoichiometry of nano-structured sol-gel-derived BaTiO3 monolithic gels[J].J. Am. Ceram. Soc., 1996, 79(11): 2983-2985.

DOI: 10.1111/j.1151-2916.1996.tb08739.x

Google Scholar

[6] G. Pfaff. Sol-gel synthesis of barium titanate powders of various compositions [J].J. Mater. Chem., 1992, 2(6): 591-594.

DOI: 10.1039/jm9920200591

Google Scholar

[7] T. Takeuchi,M. Tabuchi,K. Ado,K. Honjo,O. Nakamura,H. Kageyama,Y. Suyama,N. Ohtori,M. Nagasawa. Grain size dependence of dielectric properties of ultrafine BaTiO3 prepared by a sol-crystal method[J].J. Mater. Sci., 1997, 32(15): 4053-4060.

DOI: 10.1023/a:1018697706704

Google Scholar

[8] W.L. luan,L. Gao. Influence of pH on Properties of Nanocrystalline BaTiO3 Powder [J]. Ceramics International, 2001, 27: 645-648.

DOI: 10.1016/s0272-8842(01)00012-8

Google Scholar

[9] H.M. Rietveld, J. Appl. Crystallogr. 2 (1969) 65.

Google Scholar

[10] TOPAS, Bruker AXS, Version 3. 0, (2000).

Google Scholar

[11] JCPDS-International Centre for Diffraction Data, PCPDFWIN V. 2. 01, (1998).

Google Scholar

[12] K. Branderburg, Diamond: Visual Crystal Structure Information System, Crystal Impact GbR, Version 3. 0, (2004).

Google Scholar