The Effect of CTAB Additive on Performance of Layered Cathode Material Li0.96Na0.04Ni1/3Co1/3Mn1/3O2

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Li0.96Na0.04Ni1/3Co1/3Mn1/3O2 with CTAB as additive was synthesized. X-ray diffraction pattern reveals the product of the material with CTAB is pure phase. Scanning electron microscopy shows that the powders are average of 200 nm. Electrochemical test shows it in terms of high initial discharge capacity (175.6 mAhg-1) and exhibits good cycle performance with the capacity retention of 93.39 % after 90 cycles compared to the material has no additive (167.6 mAhg-1 and 71.18 %) at 0.1 C rate. Therefore, CTAB as additive should improve the performance of Li0.96Na0.04Ni1/3Co1/3Mn1/3O2 cathode material.

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501-504

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September 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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