Modification of Working Electrode of Dye-Sensitized Solar Cell Using TiO2 Nanopraticles/TiO2 Nanofibers/CNT Composite

Article Preview

Abstract:

The working electrode of dye-sensitized solar cell was modified using composite material of TiO2 particles/TiO2 nanofibers/CNT by doctor blade method. Structural properties of pre-cursor materials and as-prepared working electrodes were well characterized by X-ray diffraction and scanning electron microscopy. The efficiency and relevant parameters of solar cells with modified electrodes were measured. The optimized weight ratios of 1 wt.% TiO2 nanofibers derived from leucoxene and 0.01 wt.% CNT exhibited the highest improvement of DSSC efficiency with solar efficiency of 1.11% and fill factor of 0.32. The increase of current density may be originated from easier electron transfer that occurred in the device with modified TiO2 particles/TiO2 nanofibers/CNT composite.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

32-36

Citation:

Online since:

September 2013

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] W. Jarernboon, S. Pimanpang, S. Maensiri, E. Swatsitang and V. Amornkitbamrung, "Optimization of titanium dioxide film prepared by electrophoretic deposition for dye-sensitized solar cell application," Thin Solid Film, vol. 517, pp.4663-4667, 2009.

DOI: 10.1016/j.tsf.2009.02.129

Google Scholar

[2] K. H. Ko, Y. C. Lee, and Y. J. Jung, "Enhanced efficiency of dye-sensitized TiO2 solar cells (DSSC) by doping of metal ions," J. Colloid Interf. Sci., vol. 283, pp.482-487, 2005.

DOI: 10.1016/j.jcis.2004.09.009

Google Scholar

[3] L.T. Yan, F.L. Wu, L. Peng, L.J. Zhang, P.J. Li, S.Y. Dou, and T.X. Li, "Photoanode of Dye-sensitized solar cells based on a ZnO/TiO2 composite film," Int. J. Photoenergy, vol. 2012, doi: 10.1155/2012/ 613969.

DOI: 10.1155/2012/613969

Google Scholar

[4] Z. Yang, T. Xu, S. Gao, U. Welp, and W.K. Kwok, "Enhanced electron collection in TiO2 nanoparticle-based dye-sensitized solar cells by an array of metal micropillars on a planar fluorinated tin oxide anode," J. Phys. Chem. C, vol. 114, p.19151–19156, 2010.

DOI: 10.1021/jp108761k

Google Scholar

[5] S. Li, Y. Liu, G. Zhang, X. Zhao, and J. Yin, "The role of the TiO2 nanotube array morphologies in the dye-sensitized solar cells," Thin Solid Films, vol. 520, pp.689-693, 2011.

DOI: 10.1016/j.tsf.2010.12.250

Google Scholar

[6] A. S. Nair, R. Jose, Y. Shengyuanc, and S. Ramakrishna, "A simple recipe for an efficient TiO2 nanofiber-based dye-sensitized solar cell," J. Colloid Interf. Sci. vol. 353, pp.39-45, 2011.

DOI: 10.1016/j.jcis.2010.09.042

Google Scholar

[7] S. U. Lee, W. S. Choi, and B. Hong, "A comparative study of dye-sensitized solar cells added carbon nanotubes to electrolyte and counter electrodes," Sol. Energ. Mat. Sol. C. vol. 94, pp.680-685, 2010.

DOI: 10.1016/j.solmat.2009.11.030

Google Scholar

[8] E. R. Morales, N.R. Mathews, D. R. Coronadoa, C. R. Magana, D. R. Acosta, G. A. Nunez, O. S. Martinez, and X. Mathew, "Physical properties of the CNT:TiO2 thin films prepared by sol–gel dip coating," Solar Energy, vol. 86, pp.1037-1044, 2012.

DOI: 10.1016/j.solener.2011.06.027

Google Scholar

[9] T. Wirunmongkol, P. Charoenrat, N. Tonanon, S. Niyomwas, and S. Pavasupree, "Simple Hydrothermal Preparation and Dye-Sensitized Solar Cells Efficiency of Nanotubes-Nanoparticles from Thai Leucoexene Mineral," Digests 9th Eco-Energy and Materials Science and Engineering Symposium, 2011.

Google Scholar

[10] B. Tan and Y. Wu, "Dye-sensitized solar cell based on anatase TiO2 nanoparticle/nanowire composites," J. Phy. Chem, vol. 110, pp.15932-15938, 2006.

DOI: 10.1021/jp063972n

Google Scholar

[11] J. Yu, J. Fan, and B. Cheng, "Dye-sensitized solar cells based on anatase TiO2 hollow spheres/carbon nanotube composite films," J. Power Sources, vol. 196, pp.7891-7898, 2011).

DOI: 10.1016/j.jpowsour.2011.05.014

Google Scholar