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Study on the Conversion of Ammonia by Electrochemical Oxidation
Abstract:
The removal of high concentration ammonia in wastewater was investigated by an indirect electrochemical oxidation method using titanium electrodes coated with ruthenium and iridium (RuO2-IrO2-TiO2/Ti). The effect of different initial pH on ammonia removal by electrochemical oxidation was studied. The concentrations variation of ammonia, total nitrogen, nitrate nitrite, and free cholorines, chloramines was analyzed under the conditions with and without pH controlling. The results indicate that ammonia removal efficiency was higher under the moderate alkaline condition than that under neutral one. During the electrolysis process, nitrate and nitrite concentrations were very low, even below their detecting limits. The concentrations of free chlorines and chloramines were significantly affected by pH, as trichloramine and free chlorines were mainly produced in the reaction without pH controlling, while monochloramine was mainly produced in a stable alkalescene.
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1355-1361
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September 2013
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© 2013 Trans Tech Publications Ltd. All Rights Reserved
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