Experimental Measurement of Induction Period of Gypsum Precipitation in the Laminar Flow State

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The gypsum precipitation was investigated under different conditions of temperature and supersaturation, which has significant effects on the optimization of humidification-dehumidification process. The spectrophotometer was used to measure the precipitation induction period of gypsum. The primary nucleation of calcium sulphate solution was investigated with the combination of nucleation induction period and classical nucleation theory. It was found that a power relation existed between the induction period and the operation conditions.

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456-459

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September 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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[1] K. Bourouni, M. T. Chaibi, L. Tadrist, Water desalination by humidification and dehumidification of air: State of the art, Desalination 137 (2001) 167-176.

DOI: 10.1016/s0011-9164(01)00215-6

Google Scholar

[2] P. Budhiraja, A. A. Fares, Studies of scale formation and optimization of antiscalant dosing in multi-effect thermal desalination units, Desalination 220 (2008) 313-325.

DOI: 10.1016/j.desal.2007.01.036

Google Scholar

[3] S. B. Ahmed, M. Tlili, M. B. Amor, H. B. Bacha, B. Elleuch, Calcium sulphate scale prevention in a desalinatïon unit using the SMCEC technique, Desalination 167 (2004) 311-318.

DOI: 10.1016/j.desal.2004.06.140

Google Scholar

[4] A. Rahardianto, W. Y. Shih, R. W. Lee, Y. Cohen, Diagnostic characterization of gypsum scale formation and control in RO membrane desalination of brackish water. J. Membrane Sci. 279 (2006) 655-668.

DOI: 10.1016/j.memsci.2005.12.059

Google Scholar

[5] F. Alimi, H. Elfil, A. Gadri, Kinetics of the precipitation of calcium sulfate dihydrate in a desalination unit, Desalination 157 (2003) 9-16.

DOI: 10.1016/s0011-9164(03)00426-0

Google Scholar

[6] T. A. Hoang, H. M. Ang, A. L. Rohl, Effects of temperature on the scaling of calcium sulphate in pipes, Powder Tech. 179 (2007) 31-37.

DOI: 10.1016/j.powtec.2006.11.013

Google Scholar

[7] J. Franke, A. Mersmann, The influence of the operational conditions on the precipitation process, Chem. Eng. Sci. 50 (1995) 1737-1753.

DOI: 10.1016/0009-2509(95)00028-4

Google Scholar

[8] T. H. Chong, R. Sheikholeslami, Thermodynamics and kinetics for mixed calcium carbonate and calcium sulfate precipitation, Chem. Eng. Sci. 56 (2001) 5391-5400.

DOI: 10.1016/s0009-2509(01)00237-8

Google Scholar

[9] B. W. Liu, J. K. Wang, G. Zhang, Y. Liu, X. R. Huang, Study on Solution Primary Nucleation by Induction Period, J. Tianjin University 36 (2003) 553-556. (in chinese).

Google Scholar

[10] H. Q. Hu, T. Hale, X. Y. Yang, L. J. Wilson, A spectrophotometer-based method for crystallization induction time period measurement, J. Crystal Growth. 232 (2001) 86-92.

DOI: 10.1016/s0022-0248(01)01145-9

Google Scholar

[11] J. A. Dean, Lange's Handbook of Chemistry, fifteenth ed., McGraw-Hill, Inc., (1998).

Google Scholar