Preparation and Characterization of Monodispersed Magnetic Nanoparticles with Carboxylic Groups via Polymerization Induced by a Double-Bond Ended Surfactant with Acrylic Acid

Abstract:

A new method for synthesizing magnetically responsive Fe₃O₄@UA@AA nanoparticles have been reported in this paper. The superparamagnetic Fe₃O₄@UA nanoparticles were prepared via carboxyl-functionalization of 10-undecenoic acid and Fe₃O₄@UA@AA made by a polymerization of 10-undecenoic acid on the surface of nanoparticles with acrylic acid. Thus the magnetic nanoparticles were functionalized with carboxylic groups. The compositions of as-prepared nanoparticles were characterized by FTIR, TGA, TEM, VSM and conductivity titration. Under optimized experimental conditions, Fe₃O₄@UA@AA nanoparticles with diameter of about 20 nm and 0.437mmol/g of carboxyl groups and 65 emu/g of saturation magnetization were prepared successfully.

• Periodical: Advanced Materials Research (Volume 815)
• Pages: 112-115
• DOI: https://doi.org/10.4028/www.scientific.net/AMR.815.112
• Online since: October 2013
• Authors: Jing Li, Guo Lun Zhong, Wen Kai Chen, Yong Hong Wang, Hong Lei Mao, Hai Ping Xia
• Keywords: 10-Undecenoic Acid, Acrylic Acid, Fourier Transform Infrared, Magnetic Nanoparticles, Transmission Electron Microscopy (TEM)

References

[1] Yu Lu, Yadong Yin, Brian T. Mayers and Younan Xia: Nano Lett Vol. 2 (2002), p.183.

[2] Claire Corot, Philippe Robert, Jean-Marc Idée and Marc Port: Adv Drug Delivery Rev Vol. 58 (2006), p.1471.

[3] Jin Lu, Dawei Qi, Chunhui Deng, Xiangmin Zhang and Pengyuan Yang: Nanoscale Vol. 2 (2010), p.1892.

[4] He Ping, Cui Longlan, Qiang Weili, Xu Hong, Gu Chengdong: Acta Polymerica Sinica Vol 8 (2007), p.731.

[5] Maria Mikhaylova, Do Kyung Kim, Natalia Bobrysheva, Mikhail Osmolowsky, Valentin Semenov, Thomas Tsakalakos and Mamoun Muhammed: Langmuir Vol. 20 (2004), p.2472.

DOI: 10.1021/la035648e

[6] L. A. Harris, J. D. Goff, A. Y. Carmichael, J. S. Riffle, J. J. Harburn, T. G. St. Pierre and M. Saunders: Chem. Mater Vol. 15 (2003), p.1367.

DOI: 10.1021/cm020994n

[7] Xing-Can Shen, Xiu-Zhong Fang, Ying-Hua Zhou and Hong Liang: Chem Lett Vol. 33 (2004), p.1468.

[8] Nianqiang Wu, Lei Fu, Ming Su, Mohammed Aslam, Ka Chun Wong and Vinayak P. Dravid: Nano Lett Vol. 4 (2004), p.383.

[9] Unyong Jeong, Xiaowei Teng, Yong Wang, Hong Yang and Younan Xia: Adv. Mater Vol. 19 (2007), p.33.

[10] Shouhu Xuan, Lingyun Hao, Wanquan Jiang, Xinglong Gong, Yuan Hu and Zuyao Chen: J. Magn. Magn. Mater Vol. 308 (2007), p.210.

[11] Seigou K, Ahmad Y and Mitchell A W: J Colloid Interface Sci Vol. 176 (1995), p.362.