Template Assisted Growth of Zinc Oxide-Based Nanowires and Piezoelectric Properties

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In this paper, we report on the synthesis of ZnO nanowires via templated electrochemical deposition. ZnO nanowire arrays were fabricated by potentiostatic electrodeposition in track-etched polycarbonate (PC) membrane. The electrolyte was aqueous solution containing zinc nitrate precursor. The electrodeposition process involves the electroreduction of nitrate ions to alter the local pH and precipitation of the metal oxide within the pores. The morphology analysis and structure characterization of the ZnO nanowires were carried out using conventional scanning electron microscopy (SEM) and X-Ray diffraction. To check the piezoelectric characteristics of the zinc oxide nanowires, the AFM microscope is used in contact mode. The scanned area was 5µm*5µm and the affected force was 30nN. In result of scanning each nanowire with conductive AFM tip in contact mode, a current peak which had a width smaller than topography peak was fabricated. This is due to semi-conductivity and piezoelectricity characteristics of Nanowires.

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757-761

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November 2013

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] L.W. Wang and J. Song, Piezoelectric Nanogenerators Based on Zinc Oxide Nanowire Arrays, Science. 312 (2006) 242-246.

DOI: 10.1126/science.1124005

Google Scholar

[2] Z.L. Wang, Novel Nanostructures of ZnO for Nanoscale Photonics, Optoelectronics, Piezoelectricity, and Sensing. , Appl. Phys. A. 88(1) (2007) 7-15.

DOI: 10.1007/s00339-007-3942-8

Google Scholar

[3] M. Sima, I. Enculescy, E. Vsile, Growth of ZnO micro and nanowires using the template method, J. Optoelectronic. and Adv. Mater Vol. 8 (2006) 825 – 828.

Google Scholar

[4] X. Zhang, D. Li, La. Bourgeois, H. Wang, and P. A. Webley, Direct Electrodeposition of Porous Gold Nanowire Arrays for Biosensing Applications, Phys. Chem. 10 (2009) 436 – 441.

DOI: 10.1002/cphc.200800538

Google Scholar

[5] P. A. Mardini Farias, and M. B. Rodrigues Bastos, Electrochemical Behavior of Copper (II) salen in Aqueous Phosphate Buffer at the Mercury Electrode, Int. J. Electrochem. Sci., 4 (2009) 458 – 470.

Google Scholar

[6] J. Wang, Li. Gao, Hydrothermal synthesis and photoluminescence properties of ZnO nanowires, Solid State Commun. 132 (2004) 269–271.

DOI: 10.1016/j.ssc.2004.07.052

Google Scholar

[7] Zh. Liu, Ch. Liu, J. Ya, E. Lei, Controlled synthesis of ZnO and TiO2 nanotubes by chemical method and their application in dye-sensitized solar cells, Renewable Energy 36 (2011) 1177-1181.

DOI: 10.1016/j.renene.2010.09.019

Google Scholar

[8] Y. Leprince-Wang, G.Y. Wang, X.Z. Zhang, D.P. Yu, Study on the microstructure and growth mechanism of electrochemical deposited ZnO nanowires, J. Crystal Growth 287 (2006) 89–93.

DOI: 10.1016/j.jcrysgro.2005.10.049

Google Scholar

[9] M.P. Lu, M.Y. Lu, M.T. Chen, Y. Gao, L.J. Chen and Zh.L. Wang, Piezoelectric Nanogenerator Using p-Type ZnO Nanowire Arrays, Nano Lett. 9(3) (2009) 1223-1227.

DOI: 10.1021/nl900115y

Google Scholar