Synthesis and Properties Study of 1-(2-cyano-1,5-dimethyl-4-pyrryl)-2-[2-methyl-5-(10-phen-anthrenyl)-3-thienyl]Perfluorocyclopentene

Abstract:

A new photochromic diarylethene, 1-(2-cyano-1,5-dimethyl-4-pyrryl)-2-[2-methyl-5-(10-phen-anthrenyl)-3-thienyperfluorocyclopentene was synthesized and its photochromic and fluorescent properties were also systematically investigated. The results showed that this compound exhibited reversible photochromic, changing from colorless to blue after irradiation with UV light in both solution and PMMA amorphous film. The fluorescence intensity declined along with the photochromic when irradiation with UV light. However the fluorescence switch in PMMA amorphous film showed more remarkable than in solution.

• Periodical: Advanced Materials Research (Volume 830)
• Pages: 262-265
• DOI: https://doi.org/10.4028/www.scientific.net/AMR.830.262
• Online since: October 2013
• Authors: Xue Li, Jun Jie Song, Gang Liu
• Keywords: Diarylethene, Fluorescence, Phenanthrene, Photochromism

References

[1] H. Tian and S. J. Yang: Chem. Soc. Rev. Vol. 33 (2004), p.85.

[2] M. Irie: Chem. Rev. Vol. 100 (2000), p.1685.

[3] H. Dürr and H. Bouas-Laurent: Photochromism: Molecules and Systems (Elsevier, Amsterdam 1990).

[4] T. Kaieda, S. Kobatake, H. Miyasaka, M. Murakami, N. Iwai, Y. Nagata, A. Itaya and M. Irie: J. Am. Chem. Soc. Vol. 124 (2002), p. (2015).

DOI: 10.1021/ja0115722

[5] N. Tanaka, C. Okabe, K. Sakota, and M. Irie: J. Mol. Struct. Vol. 616 (2002), p.113.

[6] R. Matsushima and H. Sakaguchi: J. Photochem. Photobiol. A: Chem. Vol. 108 (1997), p.239.

[7] Y. Yokoyama: Chem. Rev. Vol. 100 (2000), p.1717.

[8] Z. Fang, S.Z. Wang, Z.F. Yang, B. Chen, F.T. Li, J.Q. Wang, S.X. Xu, Z.J. Jiang and T.R. Fang: J. Photochem. Photobiol. A: Chem. Vol. 88 (1995), p.23.

[9] A.J. Myles and N.R. Branda: J. Am. Chem. Soc. Vol. 123 (2001), p.177.

[10] K. Matsuda and M. Irie: J. Photoch. Photobiol. C Vol. 5 (2004), p.169.

[11] X. Li, W.J. Liu and G. Liu: Adv. Mater. Res. Vol. 58 (2012), p.130.

[12] X. Li, C.B. Fan and G. Liu: App. Mechan. and Mater. Vol. 164 (2012), p.255.

[13] X. Li, C.B. Fan and G. Liu: Adv. Mater. Res. Vol. 763 (2013), p.79.

[14] S.Z. Pu, H.H. Tang, B. Chen, J.K. Xu, and W.H. Huang: Mater. Lett. Vol. 60 (2006), p.3553.

[15] H. Tian, B.Z. Chen, H.Y. Tu, and K. Müllen: Adv. Mater. Vol. 17 (2002), p.918.

[16] B. Chen, M. Wang, Y. Wu, and H. Tian: Chem. Commun. Vol. 21 (2002), p.1060.